NDLI: Hydrogen Sulfide Induced Carbon Dioxide Activation by Metal-Free Dual Catalysis

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Hydrogen Sulfide Induced Carbon Dioxide Activation by Metal-Free Dual Catalysis

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Hydrogen Sulfide Induced Carbon Dioxide Activation by Metal-Free Dual Catalysis

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Francisco, Joseph S. Kumar, Manoj
Description	Author Affiliation: Kumar M ( Department of Chemistry, University of Nebraska-Lincoln, Lincoln, NE, 68588, USA.); Francisco JS ( Department of Chemistry, University of Nebraska-Lincoln, Lincoln, NE, 68588, USA. jfrancisco3@unl.edu.)
Abstract	The role of metal free dual catalysis in the hydrogen sulfide $(H_{2}S)-induced$ activation of carbon dioxide $(CO_{2})$ and subsequent decomposition of resulting monothiolcarbonic acid in the gas phase has been explored. The results suggest that substituted amines and monocarboxylic type organic or inorganic acids via dual activation mechanisms promote both activation and decomposition reactions, implying that the judicious selection of a dual catalyst is crucial to the efficient C−S bond formation via $CO_{2}$ activation. Considering that our results also suggest a new mechanism for the formation of carbonyl sulfide from $CO_{2}$ and $H_{2}S,$ these new insights may help in better understanding the coupling between the carbon and sulfur cycles in the atmospheres of Earth and Venus.
ISSN	09476539
e-ISSN	15213765
Journal	Chemistry - A European Journal
Issue Number	13
Volume Number	22
Language	English
Publisher	Wiley-VCH;ChemPubSoc Europe
Publisher Date	2016-03-18
Publisher Place	Germany
Access Restriction	Open
Subject Keyword	Carbon Compounds, Inorganic Chemistry Carbon Dioxide Hydrogen Sulfide Sulfides Catalysis
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis

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