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| Content Provider | World Health Organization (WHO)-Global Index Medicus |
|---|---|
| Author | Rieger, Bernhard Höhlein, Ignaz M. D. Kehrle, Julian Lugli, Paolo Marx, Philipp Fässler, Thomas F. Scherf, Lavinia M. Lyuleeva, Alina Helbich, Tobias |
| Description | Author Affiliation: Helbich T ( Wacker-Lehrstuhl für Makromolekulare Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747, Garching, Germany.); Lyuleeva A ( Institute for Nanoelectronics, Technische Universität München, Arcisstrasse 21, 80333, Munich, Germany.); Höhlein IM ( Wacker-Lehrstuhl für Makromolekulare Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747, Garching, Germany.); Marx P ( Wacker-Lehrstuhl für Makromolekulare Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747, Garching, Germany.); Scherf LM ( Lehrstuhl für Anorganische Chemie mit Schwerpunkt Neue Materialien, Technische Universität München, Lichtenbergstrasse 4, 85747, Garching, Germany.); Kehrle J ( Wacker-Lehrstuhl für Makromolekulare Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747, Garching, Germany.); Fässler TF ( Lehrstuhl für Anorganische Chemie mit Schwerpunkt Neue Materialien, Technische Universität München, Lichtenbergstrasse 4, 85747, Garching, Germany.); Lugli P ( Institute for Nanoelectronics, Technische Universität München, Arcisstrasse 21, 80333, Munich, Germany.); Rieger B ( Wacker-Lehrstuhl für Makromolekulare Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747, Garching, Germany. rieger@tum.de.) |
| Abstract | Herein we present the functionalization of freestanding silicon nanosheets (SiNSs) by radical-induced hydrosilylation reactions. An efficient hydrosilylation of Si−H terminated SiNSs can be achieved by thermal initiation or the addition of diazonium salts with a variety of alkene or alkyne derivatives. The radical-induced hydrosilylation is applicable for a wide variety of substrates with different functionalities, improving the stability and dispersibility of the functional SiNSs in organic solvents and potentially opening up new fields of application for these hybrid materials. |
| ISSN | 09476539 |
| e-ISSN | 15213765 |
| Journal | Chemistry - A European Journal |
| Issue Number | 18 |
| Volume Number | 22 |
| Language | English |
| Publisher | Wiley-VCH;ChemPubSoc Europe |
| Publisher Date | 2016-04-25 |
| Publisher Place | Germany |
| Access Restriction | Open |
| Subject Keyword | Chemistry |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry Catalysis |
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