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| Content Provider | World Health Organization (WHO)-Global Index Medicus |
|---|---|
| Author | Lucío, María Isabel Vázquez, Ester Ramírez, José Ramón Giulani, Angela De La Hoz, Antonio Bracamonte, Maria Victoria Prato, Maurizio Hadad, Caroline Quintana, Mildred Pichler, Federica Sánchez-migallón, Ana Tavagnacco, Claudio Fierro, Jose L. G. Herrero, María Antonia |
| Description | Author Affiliation: Lucío MI ( Departamento de Química Orgánica, Inorgánica y Bioquímica, Facultad de Ciencias y Tecnologías Químicas, IRICA Universidad de Castilla-La Mancha, Campus Universitario, 13071, Ciudad Real, Spain.); Pichler F ( Dipartimento di Scienze Chimiche e Farmaceutiche Center of Excellence for Nanostructured Materials (CENMAT) & Italian Interuniversity Consortium on Materials Science and Technology (INSTM - Unit of Trieste), Università degli Studi di Trieste, Piazzale Europa 1, 34127, Trieste, Italy.); Ramírez JR ( Departamento de Química Orgánica, Inorgánica y Bioquímica, Facultad de Ciencias y Tecnologías Químicas, IRICA Universidad de Castilla-La Mancha, Campus Universitario, 13071, Ciudad Real, Spain.); de la Hoz A ( Dipartimento di Scienze Chimiche e Farmaceutiche Center of Excellence for Nanostructured Materials (CENMAT) & Italian Interuniversity Consortium on Materials Science and Technology (INSTM - Unit of Trieste), Università degli Studi di Trieste, Piazzale Europa 1, 34127, Trieste, Italy.); Sánchez-Migallón A ( Departamento de Química Orgánica, Inorgánica y Bioquímica, Facultad de Ciencias y Tecnologías Químicas, IRICA Universidad de Castilla-La Mancha, Campus Universitario, 13071, Ciudad Real, Spain.); Hadad C ( Departamento de Química Orgánica, Inorgánica y Bioquímica, Facultad de Ciencias y Tecnologías Químicas, IRICA Universidad de Castilla-La Mancha, Campus Universitario, 13071, Ciudad Real, Spain.); Quintana M ( Departamento de Química Orgánica, Inorgánica y Bioquímica, Facultad de Ciencias y Tecnologías Químicas, IRICA Universidad de Castilla-La Mancha, Campus Universitario, 13071, Ciudad Real, Spain.); Giulani A ( Dipartimento di Scienze Chimiche e Farmaceutiche Center of Excellence for Nanostructured Materials (CENMAT) & Italian Interuniversity Consortium on Materials Science and Technology (INSTM - Unit of Trieste), Università degli Studi di Trieste, Piazzale Europa 1, 34127, Trieste, Italy.); Bracamonte MV ( Instituto de Física Universidad Autónoma de San Luis Potosí, Manuel Nava 6, Zona Universitaria, 78290, San Luis Potosí, SLP, Mexico.); Fierro JL ( Dipartimento di Scienze Chimiche e Farmaceutiche Center of Excellence for Nanostructured Materials (CENMAT) & Italian Interuniversity Consortium on Materials Science and Technology (INSTM - Unit of Trieste), Università degli Studi di Trieste, Piazzale Europa 1, 34127, Trieste, Italy.); Tavagnacco C ( Dipartimento di Scienze Chimiche e Farmaceutiche Center of Excellence for Nanostructured Materials (CENMAT) & Italian Interuniversity Consortium on Materials Science and Technology (INSTM - Unit of Trieste), Università degli Studi di Trieste, Piazzale Europa 1, 34127, Trieste, Italy.); Herrero MA ( Instituto de Física Enrique Gaviola (CONICET) and FaMAF, Universidad Nacional de Córdoba Medina Allende s/n, X5000HUA, Córdoba, Argentina.); Prato M ( Instituto de Catálisis y Petroleoquímica CSIC Cantoblanco, 28049, Madrid, Spain.); Vázquez E ( Dipartimento di Scienze Chimiche e Farmaceutiche Center of Excellence for Nanostructured Materials (CENMAT) & Italian Interuniversity Consortium on Materials Science and Technology (INSTM - Unit of Trieste), Università degli Studi di Trieste, Piazzale Europa 1, 34127, Trieste, Italy.) |
| Abstract | The synthesis of functionalised carbon nanotubes as receptors for riboflavin (RBF) is reported. Carbon nanotubes, both single-walled and multi-walled, have been functionalised with 1,3,5-triazines and p-tolyl chains by aryl radical addition under microwave irradiation and the derivatives have been fully characterised by using a range of techniques. The interactions between riboflavin and the hybrids were analysed by using fluorescence and UV/Vis spectroscopic techniques. The results show that the attached functional groups minimise the π-π stacking interactions between riboflavin and the nanotube walls. Comparison of p-tolyl groups with the triazine groups shows that the latter have stronger interactions with riboflavin because of the presence of hydrogen bonds. Moreover, the triazine derivatives follow the Stern–Volmer relationship and show a high association constant with riboflavin. In this way, artificial receptors in catalytic processes could be designed through specific control of the interaction between functionalised carbon nanotubes and riboflavin. |
| ISSN | 09476539 |
| e-ISSN | 15213765 |
| Journal | Chemistry - A European Journal |
| Issue Number | 26 |
| Volume Number | 22 |
| Language | English |
| Publisher | Wiley-VCH;ChemPubSoc Europe |
| Publisher Date | 2016-06-20 |
| Publisher Place | Germany |
| Access Restriction | Open |
| Subject Keyword | Chemistry |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry Catalysis |
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