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| Content Provider | World Health Organization (WHO)-Global Index Medicus |
|---|---|
| Author | Thanigaimani, Kaliyaperumal Razak, Ibrahim Abdul Farhadikoutenaei, Abbas Arshad, Suhana |
| Description | Author Affiliation: Thanigaimani K ( School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia.) |
| Abstract | The 4-methylbenzoate anion of the title salt, $C_{6}H_{9}N_{2}$ $^{+}·C_{8}H_{7}O_{2}$ $^{−},$ is nearly planar, with a dihedral angle of 6.26 (10)° between the benzene ring and the carboxylate group. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxylate O atoms of the anion via a pair of N—H⋯O hydrogen bonds with an R $_{2}$ $^{2}(8)$ ring motif, forming an approximately planar ion pair with a dihedral angle of 9.63 (4)° between the pyridinium and benzene rings. The ion pairs are further connected via N—H⋯O and weak C—H⋯O hydrogen bonds, forming a two-dimensional network parallel to the bc plane. |
| ISSN | 20569890 |
| e-ISSN | 16005368 |
| Journal | Acta Crystallographica Section E Structure Reports Online |
| Issue Number | Pt 1 |
| Volume Number | 69 |
| Language | English |
| Publisher | IUCr/Wiley |
| Publisher Date | 2013-01-01 |
| Publisher Place | United States |
| Access Restriction | Open |
| Subject Keyword | Crystallography |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Condensed Matter Physics Materials Science |
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