NDLI: Penikisite, $BaMg_{2}Al_{2}(PO_{4})_{3}(OH)_{3},$ isostructural with bjarebyite

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Redetermination of dipotassium trichloridostannate(II) chloride monohydrate

Reinvestigation of trilithium divanadium(III) tris(orthophosphate), $Li_{3}V_{2}(PO_{4})_{3},$ based on single-crystal X-ray data

Dihydronium tetrachromate(VI), $(H_{3}O)_{2}Cr_{4}O_{13}$

$Na_{3}Al(AsO_{4})_{2}$

Penikisite, $BaMg_{2}Al_{2}(PO_{4})_{3}(OH)_{3},$ isostructural with bjarebyite

Schaurteite, $Ca_{3}Ge(SO_{4})_{2}(OH)_{6}·3H_{2}O$

The defect scheelite-type lanthanum(III) ortho-oxidomolybdate(VI) $La_{0.667}[MoO_{4}]$

Pirquitasite, $Ag_{2}ZnSnS_{4}$

Bis[μ-4-(4-carboxyphenoxy)phthalato]bis[triaquacobalt(II)]

catena-Poly[(acetatochloridozinc)-μ-1,1′-[1,4-phenylenebis(methylene)]di-1H-imidazole]

Hexaaquacobalt(II) 2,2′-[naphthalene-1,8-diylbis(oxy)]diacetate dihydrate

trans-Dibromidotetrakis(pyridine-κN)ruthenium(II)

Tetramethylammonium aquatrichloridooxalatostannate(IV) monohydrate

$Dichlorido\{N′-[phenyl(pyridin-2-yl-κN)methylidene]isonicotinohydrazide-κ^{2}$ N′,O}zinc

$Dichlorido(2,9-dimethyl-1,10-phenanthroline-κ^{2}$ N,N′)mercury(II)

$Poly[diaqua(μ_{4}-carboxylatomethylphosphonato)(μ_{4}-carboxymethylphosphonato)pentadecamethylpentatin(IV)]$

$(Acetonitrile)\{2-[bis(pyridin-2-ylmethyl-κ^{2}$ N)amino-κN]-N-(2,6-dimethylphenyl)acetamide-κO}(perchlorato-κO)zinc $(acetonitrile)\{2-[bis(pyridin-2-ylmethyl-κ^{2}$ N)amino-κN]-N-(2,6-dimethylphenyl)acetamide-κO}zinc tris(perchlorate)

$Diaqua(5,10,15,20-tetraphenylporphyrinato-κ^{4}$ N)magnesium–18-crown-6 (1/1)

trans-Dibromidobis(3-methylpyridine-κN)copper(II)

cis-Dichlorido(dimethyl sulfoxide-κS)(N,N,N′,N′-tetramethylguanidine-κN′′)platinum(II)

$catena-Poly[[[(2,2′-bipyridine-κ^{2}$ $N,N′)manganese(II)]-μ-(2,5-dichloro-3,6-dioxocyclohexa-1,4-diene-1,4-diolato)-κ^{4}$ O $^{1},O$ $^{6}:O$ $^{3},O$ $^{4}]$ ethanol disolvate]

$\{Bis[N,N′-dicyclohexyl-N′′,N′′-bis(trimethylsilyl)guanidinato-κ^{2}N,N′]neodymium(III)\}di-μ-chlorido-[bis(tetrahydrofuran-κO)lithium]$

Bis(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κO)tetrakis(methanol-κO)calcium methanol tetrasolvate

catena-Poly[[[triaqua[3-(4-carboxyphenoxy)phthalato-κO $^{2}]manganese(II)]-μ-4,4′-bipyridine-κ^{2}$ N:N′] 4,4′-bipyridine monosolvate dihydrate]

$catena-Poly[[bis(μ_{2}-1,4,7,10,13,16-hexaoxacyclooctadecane)dipotassium]-μ_{2}-iodido-(iodidocadmium)-di-μ_{2}-iodido-(iodidocadmium)-μ_{2}-iodido]$

μ-Oxalato-bis[bis(triphenylphosphine)copper(I)] dichloromethane $disolvate^{1}$

Diaqua(5-carboxybenzene-1,3-dicarboxylato-κO $^{1})[8-ethyl-5-oxo-2-(piperazin-4-ium-1-yl)-5,8-dihydropyrido[2,3-d]pyrimidine-6-carboxylato-κ^{2}$ O $^{5},O$ $^{6}]zinc$ monohydrate

Bis(2-amino-4-methylpyrimidin-1-ium) hexaaquacobalt(II) disulfate dihydrate

$Bis(3-aminopyrazine-2-carboxylato-κ^{2}$ N $^{1},O)diaquacobalt(II)$

Bis(acetyl-acetonato-κ(2)O,O')bis-(pyridine-κN)nickel(II) dihydrate.

Bis(diethylamido-κN)(diethylamine-κN)bis(2,6-diisopropylphenylamido-κN)zirconium(IV)

Di-μ-chlorido-bis[(2,2′-bipyridine-5,5′-dicarboxylic $acid-κ^{2}$ N,N′)chloridocopper(II)] dimethylformamide tetrasolvate

$cis-Bis(1,10-phenanthroline-κ^{2}$ N,N′)bis(pyridin-4-amine-κN $^{1})ruthenium(II)$ $bis(hexafluoridophosphate)^{1}$

$cis-Bis(2,2′-bipyridine-κ^{2}N,N′)bis(pyridin-4-amine-κN^{1})ruthenium(II)$ bis(hexafluoridophosphate) acetonitrile monosolvate

(4'-Ethynyl-2,2':6',2''-terpyridine)(2,2':6',2''-terpyridine)-ruthenium(II) bis-(hexa-fluoridophosphate) acetonitrile disolvate.

μ-2,3,5,6-Tetrakis(pyridin-2-yl)pyrazine-bis[(2,2′:6′,2′′-terpyridine)ruthenium(II)] tetrakis(hexafluoridophosphate) acetonitrile tetrasolvate

$Di-μ-thiosemicarbazide-κ^{4}$ S:S-bis[chloridobis(triphenylphosphane-κP)silver(I)]

$Poly[bis(μ_{2}-5-\{4-[(1H-imidazol-1-yl)methyl]phenyl\}tetrazolato)zinc]$

$Di-μ-chlorido-bis\{[2-(di-tert-butylphosphanyl)biphenyl-3-yl-κ^{2}$ C $^{3},P]palladium(II)\}$ dichloromethane disolvate

$catena-Poly[μ_{2}-iodido-diiodidobis(μ_{3}-pyridine-2-thione-κ^{3}$ $S:S:S)(μ_{2}-pyridine-2-thione-κ^{2}$ S:S)tricopper(I)]

Tetrabromido[4-(triphenylphosphanyloxy)butyl]tellurium acetonitrile monosolvate

$Bis(2,2′,2′′-nitrilotriacetamide-κ^{3}$ O,N,O′)nickel(II) dinitrate tetrahydrate

$catena-Poly[[bis(4-methylpyridine-κN)cobalt(II)]-di-μ-dicyanamido-κ^{2}$ N $^{1}:N$ $^{5}]$

$Dichloridodi-μ_{2}-hydroxido-di-μ_{3}-oxido-octaphenyltetratin(IV)$ dimethyl sulfoxide disolvate

rac-Dichlorido[3-ethoxy-3-(1-ethyl-1H-benzimidazol-2-yl)-2,3-dihydro-1H-pyrrolo[1,2-a]benzimidazole]copper(II)

$Diaquabis(1H-imidazole-4-carboxylato-κ^{2}$ N $^{3},O)cobalt(II)$

3,5-Diphenyl-1,2,4-dithiazolium tetrabromidoferrate(III)

Bis{2-[(2,4,6-trimethylphenyl)iminomethyl]pyrrol-1-ido}palladium(II)

[μ-6,9-Bis(carboxylatomethyl)-3,12-bis(carboxymethyl)-3,6,9,12-tetraazatetradecanedioato]bis[aquacobalt(II)] tetrahydrate

$(4-Chloroacetanilido-κ^{2}$ $N,O)bis[2-(pyridin-2-yl)phenyl-κ^{2}$ C $^{1},N]iridium(III)$

$(2-Amino-7-methyl-4-oxidopteridine-6-carboxylato-κ^{3}$ O $^{4},N$ $^{5},O$ $^{6})aqua(ethane-1,2-diamine-κ^{2}$ N,N′)nickel(II) dihydrate

(E)-2-[(Furan-2-yl)methylidene]-7-methyl-2,3,4,9-tetrahydro-1H-carbazol-1-one

rac-2,3-Dibromopropionamide

A second monoclinic polymorph of N-(2,4-dinitrophenyl)-2,4-dinitroaniline

N-(7-Dibromomethyl-5-methyl-1,8-naphthyridin-2-yl)acetamide–pyrrolidine-2,5-dione (1/1)

3-Benzyl-4-ethyl-1H-1,2,4-triazole-5(4H)-thione

Isopropyl 2,3,4,6-tetra-O-acetyl-β-d-glucopyranoside

n-Propyl 2,3,4,6-tetra-O-acetyl-β-d-glucopyranoside

2-Chlorobenzene-1,4-diaminium bis(dihydrogenphosphate)

(1SR,3RS,3aSR,6aRS)-Methyl 5-methyl-4,6-dioxo-3-[2-(trifluoromethyl)phenyl]octahydropyrrolo[3,4-c]pyrrole-1-carboxylate

1-{(Z)-[2-Methoxy-5-(trifluoromethyl)anilino]methylidene}naphthalen-2(1H)-one

$6-Bromo-1-methyl-4-[2-(1-phenylethylidene)hydrazinylidene]-3,4-dihydro-1H-2λ^{6},1-benzothiazine-2,2-dione$

$3-Chloro-1-methyl-4-[2-(3-phenylallylidene)hydrazinylidene]-3,4-dihydro-1H-2λ^{6},1-benzothiazine-2,2-dione$

2,6-Dimethylphenyl acridine-9-carboxylate

(Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithioate

3-({4-[(2-Methylbenzylidene)amino]-5-sulfanylidene-1H-1,2,4-triazol-3-yl}methyl)-1,3-benzoxazol-2(3H)-one

6-Nitro-1,3-benzothiazole-2(3H)-thione

N-(β-Carboxyethyl)-α-isoleucine

4-[Amino(3-methylphenyl)methylidene]-2-(3-methylphenyl)-1H-imidazol-5(4H)-one ethanol hemisolvate

9-[3-(Dimethylamino)propyl]-10,10-dimethyl-9,10-dihydroanthracen-9-ol

2-[5-(2-Fluorophenyl)-3-isobutyl-1H-pyrazol-1-yl]benzoic acid

(1E,4E)-1,5-Bis[2-(trifluoromethyl)phenyl]penta-1,4-dien-3-one

Benzyl N-[(Z)-(1-methyl-2-sulfanylpropylidene)amino]carbamodithioate

2,4,6,8-Tetrakis(2-fluorophenyl)-3,7-diazabicyclo[3.3.1]nonan-9-one

Methyl 6-ethoxy-3-phenyl-3a,4-dihydro-3H-chromeno[4,3-c]isoxazole-3a-carboxylate

3-(2-Methylphenyl)-3a,4-dihydro-3H-chromeno[4,3-c]isoxazole-3a-carbonitrile

Diethyl [(2-chloroanilino)(1,3-diphenyl-1H-pyrazol-4-yl)methyl]phosphonate

$1-(4-Chlorophenyl)-2-[tris(4-methylphenyl)-λ^{5}-phosphanylidene]butane-1,3-dione$

2-(2H-Indazol-2-yl)-1-phenylethanone

(2,3-Difluorophenyl)(4-tosylpiperazin-1-yl)methanone

3,3′,5,5′-Tetra-tert-butyl-2′-hydroxy-[1,1′-biphenyl]-2-yl 4-methylbenzenesulfonate

(E)-3-Amino-4-(2-phenylhydrazinylidene)-1H-pyrazol-5(4H)-one

3-[2-Cyclopropyl-1-(2-fluorophenyl)-2-oxoethyl]-5-(4-methylsulfanylbenzylidene)-1,3-thiazolidine-2,4-dione

2-(2-Hydroxy-2-phenylethyl)-1-methylcyclopropan-1-ol

Ethyl 3-[6-(4-methoxybenzenesulfonamido)-2H-indazol-2-yl]propanoate monohydrate

(6-Methoxy-2-oxo-2H-chromen-4-yl)methyl morpholine-4-carbodithioate

2-[(2-Hydroxynaphthalen-1-yl)methylideneamino]-5,6,7,8-tetrahydro-4H-cyclohepta[b]thiophene-3-carbonitrile

2-(Naphthalene-2-sulfonamido)-3-phenylpropanoic acid

P,P-Bis[4-(dimethylamino)phenyl]-N,N-bis(propan-2-yl)phosphinic amide

5-Benzoyl-4-(4-fluorophenyl)-3,4-dihydropyrimidin-2(1H)-one

4-Methyl-6-(piperidin-1-yl)pyrimidin-2-amine

Ethyl 5-bromonaphtho[2,1-b]furan-2-carboxylate

(E)-4-Bromo-N-{(E)-3-[(4-bromo-2-methylphenyl)imino]butan-2-ylidene}-2-methylaniline

$1-Ethyl-4-\{2-[1-(4-methylphenyl)ethylidene]hydrazinylidene\}-3,4-dihydro-1H-2λ^{6},1-benzothiazine-2,2-dione$

2,2′-Dihydroxy-N,N′-(ethane-1,2-diyl)dibenzamide

$endo,endo-Tetracyclo[6.2.1.1^{3,6}.0^{2,7}]dodeca-9-en-anti-11-yl$ 4-bromobenzoate

$1,4,6,9-Tetra-tert-butyl-2,7-dioxatricyclo[6.3.0.0^{3,6}]deca-3,8-diene$

tert-Butyl 4-(3,4-dichloroanilino)piperidine-1-carboxylate

4-(4-Nitrobenzyl)pyridinium 3-carboxy-4-hydroxybenzenesulfonate

Methyl 2,4-dihydroxy-5-(4-nitrobenzamido)benzoate

[2,7-Dihydroxy-8-(4-phenoxybenzoyl)naphthalen-1-yl](4-phenoxyphenyl)methanone

1-Benzoylnaphthalene-2,7-diyl dibenzoate

2-(Carboxymethyl)imidazo[1,2-a]pyridin-1-ium chloride

4-(Octyloxy)phenyl 2-oxo-2H-chromene-3-carboxylate

Bis(4-methoxybenzylammonium) dihydrogen diphosphate

1-Cyclopropyl-2-(2-fluorophenyl)-5-(4-fluorophenyl)-3-phenylpentane-1,5-dione

(Z)-4-Bromo-N-{(Z)-3-[(4-bromo-2,6-diisopropylphenyl)imino]butan-2-ylidene}-2,6-diisopropylaniline

meso-4,4′-Difluoro-2,2′-{[(3aR,7aS)-2,3,3a,4,5,6,7,7a-octahydro-1H-1,3-benzimidazole-1,3-diyl]bis(methylene)}diphenol

(7aR)-1-[(2R,5S,E)-6-Hydroxy-5,6-dimethylhept-3-en-2-yl]-7a-methylhexahydro-1H-inden-4(2H)-one

3-Methyl-1-tosyl-1H-indole-2-carbaldehyde

Ethyl N-(2-benzoyl-3-oxo-3-phenylpropanoyl)carbamate

Methyl 2,4-dihydroxy-5-(2-methylpropanamido)benzoate

N-(4,4′-Dibromo-[1,1′-biphenyl]-2-yl)benzamide

(S)-2,2′-Dihydroxy-N,N′-(6-hydroxyhexane-1,5-diyl)dibenzamide

Dimethyl 2-[(acridin-9-yl)methylidene]malonate

[(1R,3S)-2,2-Dichloro-3-(hydroxymethyl)cyclopropyl]methanol

5-(2,5-Dioxooxolan-3-yl)-8-methyl-3,3a,4,5-tetrahydro-1H-naphtho[1,2-c]furan-1,3-dione

N-(5-Amino-1H-1,2,4-triazol-3-yl)pyridine-2-carboxamide

2-Chloro-N-methyl-N-[2-(methylamino)phenyl]acetamide

Methyl N-hydroxy-N-(2-methylphenyl)carbamate

4-Hydroxy-1-methyl-3-phenylquinolin-2(1H)-one

Olanzapinium dipicrate

4-Amino-N-(4,6-dimethylpyrimidin-2-yl)benzenesulfonamide–2-nitrobenzoic acid (1/1)

rac-Methyl (1R,3′S)-1′,1′′-dimethyl-2,2′′-dioxo-2H-dispiro[acenaphthylene-1,2′-pyrrolidine-3′,3′′-indoline]-4′-carboxylate

Glycine–d-tartaric acid (1/1)

1-tert-Butyl 2-ethyl 5-bromo-3-(thiophen-2-ylcarbonyl)-1H-indole-1,2-dicarboxylate

2-(1H-Imidazol-1-yl)-4-[3-(trifluoromethyl)phenyl]-1,3-thiazole

1-Tosyl-4-[2-(trifluoromethyl)benzyl]piperazine

3-Chloro-4-fluoroanilinium picrate

3-(3,4-Dimethoxybenzyl)chroman-4-one

[8-(4-Phenoxybenzoyl)-2,7-bis(propan-2-yloxy)naphthalen-1-yl](4-phenoxyphenyl)methanone

rac-1-[6-Hydroxy-4-(4-methoxyphenyl)-3,6-dimethyl-4,5,6,7-tetrahydro-2H-indazol-5-yl]ethanone

1-Phenyl-2-[4-(trifluoromethyl)phenyl]-1H-benzimidazole

3-[2-(Triphenylphosphanylidene)acetyl]-2H-chromen-2-one

2,2-Dimethyl-2,3-dihydro-1H-perimidine

4-(1-Methylethyl)-N-((E)-4-{[1-(prop-2-en-1-yl)-1H-1,2,3-triazol-4-yl]methoxy}benzylidene)aniline

Orphenadrinium dihydrogen citrate

3′′-(2-Fluorobenzylidene)-4′-(2-fluorophenyl)-1′-methyldispiro[acenaphthylene-1,2′-pyrrolidine-3′,1′′-cyclopentane]-2,2′′-dione

Pyrimidine-2,4-diamine acetone monosolvate

5-(4-Chlorophenyl)-1-cyclopropyl-2-(2-fluorophenyl)-3-phenylpentane-1,5-dione

2-Chloro-8,8-dimethyl-8,9-dihydro-7H-chromeno[2,3-b]quinoline-10,12-dione

8,8-Dimethyl-8,9-dihydro-7H-chromeno[2,3-b]quinoline-10,12-dione

5,11-Dimethyl-6,12-dimethoxyindolo[3,2-b]carbazole

5′′-(4-Methoxybenzylidene)-1′-(4-methoxyphenyl)-1′′-methyl-1′,2′,3′,5′,6′,7′,8′,8a′-octahydrodispiro[acenaphthylene-1,3′-indolizine-2′,3′′-piperidine]-2,4′′(1H)-dione

3-[2-(5-tert-Butyl-1,2-oxazol-3-yl)hydrazinylidene]chroman-2,4-dione

2-(Acetoxymethyl)benzoic acid

4-[Bis(4-fluorophenyl)methyl]-1-[(2E)-3-phenylprop-2-en-1-yl]piperazin-1-ium 3-carboxypropanoate

1H-Benzotriazol-1-yl 4-{(E)-[4-(dimethylamino)phenyl]diazenyl}benzoate

(2S,4R)-2-[(1R)-1-(4-Bromophenyl)-2-nitroethyl]-4-ethylcyclohexanone

2-[4-(Trifluoromethoxy)phenyl]-1H-benzimidazole

(6R*,10R*)-Dimethyl 1,4-dioxaspiro[4.5]decane-6,10-dicarboxylate

4′-Cyanobiphenyl-4-yl 7-diethylamino-2-oxo-2H-chromene-3-carboxylate

(6bS*,14R*,14aR*)-Methyl 14-(4-methylphenyl)-7-oxo-6b,6c,7,12b,14,14a-hexahydro-1H-pyrano[3,2-c:5,4-c′]dichromene-14a-carboxylate

2-(4-Methoxyphenyl)-1-phenyl-1H-benzimidazole

7-Methoxy-2-phenylchroman-4-one

$14-Ethoxy-4,6,9-trimethyl-8,12-dioxa-4,6-diazatetracyclo[8.8.0.0^{2,7}.0^{13,18}]octadeca-2(7),13,15,17-tetraene-3,5,11-trione$

(4R*,4aR*,7aS*)-5-Oxo-6-phenyl-4a,5,6,7,7a,8-hexahydro-4H-furo[2,3-f]isoindole-4-carboxylic acid

$(1S,3R,8R,9S,11R)-2,2,10,10-Tetrachloro-3,7,7,11-tetramethyltetracyclo[6.5.0.0^{1,3}.0^{9,11}]tridecane$

(E)-N′-(4-Chlorobenzylidene)-2-methoxybenzohydrazide

(E)-2-Methoxy-N′-(2,4,6-trihydroxybenzylidene)benzohydrazide

Methyl 4′-(4-fluorophenyl)-1′-methyl-3′-nitromethyl-2-oxospiro[indoline-3,2′-pyrrolidine]-3′-carboxylate

4-Methylpyridinium 4-hydroxybenzoate

rac-4a,10b-cis,10b,5c-trans-5-(7-Methyl-2-oxo-2H-chromen-4-yl)-3,4,4a,5,6,10b-hexahydro-2H-pyrano[3,2-c]quinoline

9-(2,4-Dinitrophenyl)-3,3,6,6-tetramethyl-3,4,5,6,7,9-hexahydro-1H-xanthene-1,8(2H)-dione

rac-[2-(Dicyclohexylphosphanyl)phenyl](phenyl)phosphinic diisopropylamide–borane hemihydrate

(Z)-3-(1-Hydroxy-3-oxobut-1-enyl)-6-nitro-2H-chromen-2-one

Benzyl 2-(benzylsulfanyl)benzoate

2-Benzhydryl-6-tert-butyl-4-methylphenol

rac-5-Bromo-N-benzylisatincreatinine ethanol monosolvate

rac-N-Benzylisatincreatinine (unknown solvate)

N,N,N′,N′,N′′-Pentamethyl-N′′-[3-(trimethylazaniumyl)propyl]guanidinium bis(tetraphenylborate)

Ethyl 4-hydroxy-1-methyl-5-oxo-2-phenylpyrrolidine-3-carboxylate 1.25-hydrate

4-[5-(4-Chlorophenyl)-3-methyl-1H-pyrazol-1-yl]benzenesulfonamide

9-(3,4-Dimethoxyphenyl)-3,3,6,6-tetramethyl-1,2,3,4,5,6,7,8,9,10-decahydroacridine-1,8-dione

Ethyl 4-anilino-2,6-bis(4-fluorophenyl)-1-phenyl-1,2,5,6-tetrahydropyridine-3-carboxylate

The charge-transfer complex 1-aminoanthraquinone–7,7′,8,8′-tetracyanoquinodimethane (1/1)

Desoxyhemigossypol 6-methyl ether

Acetonyltriphenylphosphonium nitrate

3-{5-Ethoxycarbonyl-1-[3-(2-oxopyrrolidin-1-yl)propyl]-1H-benzimidazol-2-yl}benzoic acid

Phenyl acridine-9-carboxylate

1,3-Bis[(tert-butylsulfanyl)methyl]-2,4,6-trimethylbenzene

$1-[3-(Naphthalen-1-yl)phenyl]naphthalene^{1}$

$2-[3-(Naphthalen-2-yl)phenyl]naphthalene^{1}$

6-Chloro-2,4-bis(dimethylamino)-1,3,5-trimethylborazine

A second monoclinic polymorph of (E)-phenyl(pyridin-2-yl)methanone oxime

Methyl 2-bromo-3-(4-chlorobenzenesulfonamido)benzoate

8-Bromo-3-phenyl-3a,4-dihydro-3H-chromeno[4,3-c]isoxazole-3a-carbonitrile

$3β-Acetoxy-19-hydroxy-Δ^{5}-pregnen-20-one$

1-(4-{2-[(E)-3-(4-Chlorophenyl)-3-oxoprop-1-en-1-yl]phenoxy}butyl)-1H-indole-3-carbaldehyde

(1S,3aS,4S,7aS)-Ethyl 1-benzyl-2-(4-methoxybenzyl)-6,7-dimethyl-3-oxo-2,3,3a,4,5,7a-hexahydro-1H-isoindole-4-carboxylate dichloromethane monosolvate

2-Hydroxy-3-methoxymethyl-5-methylbenzaldehyde

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Penikisite, $BaMg_{2}Al_{2}(PO_{4})_{3}(OH)_{3},$ isostructural with bjarebyite

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Downs, Robert T. Yang, Hexiong Bowman, Michael G.
Description	Author Affiliation: Bowman MG ( Department of Geosciences, University of Arizona, 1040 E. 4th Street, Tucson, Arizona 85721-0077, USA.)
Abstract	The bjarebyite group of minerals, characterized by the general formula BaX $_{2}$ Y $_{2}(PO_{4})_{3}(OH)_{3},$ with X = Mg, $Fe^{2+}$ or $Mn^{2+},$ and Y = Al or $Fe^{3+},$ includes five members: bjarebyite $BaMn^{2+}$ $_{2}Al_{2}(PO_{4})_{3}(OH)_{3},$ johntomaite $BaFe^{2+}$ $_{2}Fe^{3+}$ $_{2}(PO_{4})_{3}(OH)_{3},$ kulanite $BaFe^{2+}$ $_{2}Al_{2}(PO_{4})_{3}(OH)_{3},$ penikisite $BaMg_{2}Al_{2}(PO_{4})_{3}(OH)_{3},$ and perloffite $BaMn^{2+}$ $_{2}Fe^{3+}$ $_{2}(PO_{4})_{3}(OH)_{3}.$ Thus far, the crystal structures of all minerals in the group, but penikisite, have been determined. The present study reports the first structure determination of penikisite (barium dimagnesium dialuminium triphosphate trihydroxide) using single-crystal X-ray diffraction data of a crystal from the type locality, Mayo Mining District, Yukon Territory, Canada. Penikisite is isotypic with other members of the bjarebyite group with space group $P2_{1}/m,$ rather than triclinic (P1 or P-1), as previously suggested. Its structure consists of edge-shared $[AlO_{3}(OH)_{3}]$ octahedral dimers linking via corners to form chains along [010]. These chains are decorated with $PO_{4}$ tetrahedra (one of which has site symmetry m) and connected along [100] via edge-shared $[MgO_{5}(OH)]$ octahedral dimers and eleven-coordinated $Ba^{2+}$ ions (site symmetry m), forming a complex three-dimensional network. O—H⋯O hydrogen bonding provides additional linkage between chains. Microprobe analysis of the crystal used for data collection indicated that Mn substitutes for Mg at the 1.5% (apfu) level.
ISSN	20569890
e-ISSN	16005368
Journal	Acta Crystallographica Section E Structure Reports Online
Issue Number	Pt 2
Volume Number	69
Language	English
Publisher	IUCr/Wiley
Publisher Date	2013-02-01
Publisher Place	United States
Access Restriction	Open
Subject Keyword	Crystallography
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics Materials Science

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