NDLI: Crystal structure of (2,11-diaza[3.3](2,6)pyridinophane-κ $^{4}$ N,N′,N′′,N′′′)(1,6,7,12-tetraazaperylene-κ $^{2}$ N $^{1},N$ $^{12})ruthenium(II)$ bis(hexafluoridophosphate) acetonitrile 1.422-solvate

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Year: 2014 Volume: 70

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μ-Oxalato-bis[bis(triphenylphosphine)copper(I)] dichloromethane disolvate. Corrigendum

Crystal structure of the magnesium salt of the herbicide 2,4-D: pentaaqua[(2,4-dichlorophenoxy)acetato-κO]magnesium (2,4-dichlorophenoxy)acetate hemihydrate

Crystal structure of $bis(2-\{[(pyridin-2-yl)methylidene]amino\}benzoato-κ^{3}$ N,N′,O)cobalt(II) N,N-dimethylformamide sesquisolvate

Crystal structure of 1-benzyl-4-(4-chlorophenyl)-2-imino-1,2,5,6,7,8,9,10-octahydrocycloocta[b]pyridine-3-carbonitrile

Crystal structure of 1,8-dibenzoyl-2,7-diphenoxynaphthalene

Crystal structure of $cyclo-bis(μ_{4}-2,2-diallylmalonato-κ^{6}$ O $^{1},O$ $^{3}:O$ $^{3}:O$ $^{1′},O$ $^{3′}:O$ $^{1′})tetrakis(triphenylphosphane-κP)tetrasilver(I)$

Crystal structures of isotypic poly[bis(benzimidazolium) [tetra-μ-iodido-stannate(II)]] and poly[bis(5,6-difluorobenzimidazolium) [tetra-μ-iodido-stannate(II)]]

Crystal structures and hydrogen bonding in the co-crystalline adducts of 3,5-dinitrobenzoic acid with 4-aminosalicylic acid and 2-hydroxy-3-(1H-indol-3-yl)propenoic acid

Crystal structure of a samarium(III) nitrate chain cross-linked by a bis-carbamoylmethylphosphine oxide ligand

Crystal structure of (±)-(3aR,5R,8bR)-5-hydroperoxy-2-phenyl-6-tosyl-4,5,6,8b-tetrahydropyrrolo[3,4-e]indole-1,3(2H,3aH)-dione

Crystal structure of $catena-poly[[potassium-tri-μ-dimethylacetamide-κ^{6}$ O:O] iodide]

Crystal structures of (E)-(3-ethyl-1-methyl-2,6-diphenylpiperidin-4-ylidene)amino phenyl carbonate and (E)-(3-isopropyl-1-methyl-2,6-diphenylpiperidin-4-ylidene)amino phenyl carbonate

Crystal structures of 4-(pyrimidin-2-yl)piperazin-1-ium chloride and 4-(pyrimidin-2-yl)piperazin-1-ium nitrate

Crystal structure of anhydrous $poly[bis(μ_{2}-sarcosinato-κ^{3}$ O,N:O′)copper(II)]

Crystal structure of bis(1,3-bis{[(1H-pyrrol-2-yl)methylidene]amino-κN}propan-2-olato-κO)manganese(III) nitrate methanol monosolvate

Crystal structure of 2-(1,3,7,9-tetramethyl-2,4,6,8-tetraoxo-1,2,3,4,6,7,8,9-octahydropyrido[2,3-d:6,5-d′]dipyrimidin-5-yl)benzamide dimethylformamide hemisolvate

Crystal structures of $trans-acetyldicarbonyl(η^{5}-cyclopentadienyl)(dimethylphenylphosphane)molybdenum(II)$ and $trans-acetyldicarbonyl(η^{5}-cyclopentadienyl)(ethyldiphenylphosphane)molybdenum(II)$

Crystal structure of bis[4-(dimethylamino)pyridinium] bis(2-nitrobenzoate) trihydrate

Crystal structure of (E)-1,3-dimethyl-2-[3-(3-nitrophenyl)triaz-2-en-1-ylidene]-2,3-dihydro-1H-imidazole

Crystal structure of 7-phenyl-7-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dien-1-yl)heptanoate 1,3-dihydroxy-2-(hydroxymethyl)propan-2-aminium monohydrate: a new solid form of seratrodast

Crystal structure of 2-pentyloxybenzamide

Crystal structure of tris(ethylenediammonium) hexasulfatopraseodymium(III) hexahydrate

Crystal structure of 3-{1′-[3,5-bis(trifluoromethyl)phenyl]ferrocenyl}-4-bromothiophene

Crystal structure of nitrido[5,10,15,20-tetrakis(4-methylphenyl)porphyrinato]manganese(V)

Crystal structure of the cage derivative $pentacyclo[5.4.0.0^{2,6}.0^{3,10}.0^{5,9}]undeca-8,11-dione$ ethylene dithioketal

Crystal structure of 2-ethyl-3-(4-fluorophenylsulfonyl)-5,7-dimethyl-1-benzofuran

Crystal structure of $bis\{2-[(E)-(4-fluorobenzyl)iminomethyl]phenolato-κ^{2}$ N,O}nickel(II)

Crystal structure of 4-aminopyridinium 5-(5-chloro-2,4-dinitrophenyl)-1,3-dimethyl-2,6-dioxo-1,2,3,6-tetrahydropyrimidin-4-olate hemihydrate

Crystal structure of dimethyl 3,3′-[(4-chlorophenyl)methylene]bis(1H-indole-2-carboxylate)

Crystal structure of 1-(2-chloroacetyl)-2,6-bis(4-fluorophenyl)-3,3-dimethylpiperidin-4-one

Crystal structure of (2,11-diaza[3.3](2,6)pyridinophane-κ $^{4}$ N,N′,N′′,N′′′)(1,6,7,12-tetraazaperylene-κ $^{2}$ N $^{1},N$ $^{12})ruthenium(II)$ bis(hexafluoridophosphate) acetonitrile 1.422-solvate

Crystal structure of $bis\{μ-4,4′-[1,3-phenylenebis(oxy)]dibenzoato-κ^{4}$ $O,O′:O′′,O′′′\}bis[(1,10-phenanthroline-κ^{2}$ N,N′)zinc(II)] dihydrate

Crystal structure of bis{μ-2-[(dimethylamino)methyl]ferroceneselenolato}bis[chloridopalladium(II)]

Crystal structure of $azido(η^{5}-cyclopentadienyl)bis(triphenylphosphane-κP)ruthenium(II)$ dichloromethane hemisolvate

Crystal structure of $[2-(\{4-[2,6-bis(pyridin-2-yl)pyridin-4-yl]phenyl\}(methyl)amino)ethanol-κ^{3}$ N,N′,N′′]bis(thiocyanato-κN)zinc N,N-dimethylformamide monosolvate

Crystal structure of $tetrakis(μ-n-butyrato-κ^{2}$ O:O′)bis[chloridorhenium(III)](Re—Re)

Crystal structure of bromidobis(naphthalen-1-yl)antimony(III)

Crystal structure of [2,6-bis(adamantan-1-yl)-4-tert-butylphenolato-κO]dimethylaluminium(III)

Crystal structure of $di-μ-methanolato-bis\{[N′-(1-benzoylprop-1-en-2-yl)thiophene-2-carbohydrazidato-κ^{3}$ O,N′,O′]oxidovanadium(V)}

Crystal structure of bis[4-(4-chlorobenzyl)pyridine-κN]bis(thiocyanato-κN)zinc

Crystal structure of tetraaquabis(8-chloro-9,10-dioxo-9,10-dihydroanthracene-1-carboxylato-κO $^{1})cobalt(II)$ dihydrate

Crystal structure of 5-chloro-3-(4-fluorophenylsulfinyl)-2,4,6-trimethyl-1-benzofuran

Crystal structure of 4-chloro-N-{[1-(4-chlorobenzoyl)piperidin-4-yl]methyl}benzamide monohydrate

Crystal structure of (3R)-3-benzyl-4-[(tert-butoxycarbonyl)amino]butanoic acid

Crystal structure of 4-amino-1-benzyl-1,2,4-triazolin-5-one

Crystal structure of 5,10,15-triphenyl-20-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrin

Crystal structure of 2-chloro-1-(6-fluoro-3,4-dihydro-2H-chromen-2-yl)ethanone

Crystal structure of 3-(3-oxo-2,3,4,4a,5,6-hexahydrobenzo[h]cinnolin-2-yl)propionic acid

Crystal structure of the charge-transfer complex 2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamide–pyrazine-2,3,5,6-tetracarbonitrile (2/1)

Crystal structure of (E)-13-{4-[(Z)-2-cyano-2-(3,4,5-trimethoxyphenyl)ethenyl]phenyl}parthenolide methanol hemisolvate

Crystal structure of (pyridin-2-ylmethylidene)(triphenylmethyl)amine

Crystal structure of (R)-2′-benzyloxy-[1,1′-binaphthalen]-2-yl trifluoromethanesulfonate

Crystal structure of 5,5′-[(4-fluorophenyl)methylene]bis[6-amino-1,3-dimethylpyrimidine-2,4(1H,3H)-dione]

Crystal structure of 4,4-dibutyl-2-phenyl-3,4-dihydroquinazoline

Crystal structure of 2-[4-(methylsulfanyl)quinazolin-2-yl]-1-phenylethanol

Crystal structure of trimethylammonium 5-(2,4-dinitrophenyl)-1,3-dimethyl-2,6-dioxo-1,2,3,6-tetrahydropyrimidin-4-olate

Crystal structure of (E)-2-(2-{5-[(2-acetoxyethyl)(methyl)amino]thiophen-2-yl}vinyl)-3-methylbenzothiazolium iodide monohydrate

Crystal structure of 4-{[(1H-1,2,4-triazol-1-yl)methyl]sulfanyl}phenol

Crystal structure of N′-hydroxypyrimidine-2-carboximidamide

Crystal structure of 4-cyclohexyl-1-(propan-2-ylidene)thiosemicarbazide

Crystal structure of flufenoxuron: a benzoylurea pesticide

Crystal structure of 6-(4-chlorophenyl)-6a-nitro-6,6a,6b,7,9,11a-hexahydrospiro[chromeno[3′,4′:3,4]pyrrolo[1,2-c]thiazole-11,11′-indeno[1,2-b]quinoxaline] chloroform monosolvate

Crystal structure of 4-chloro-2-[(5-ethoxy-1,3,4-thiadiazol-2-yl)methyl]-5-(piperidin-1-yl)pyridazin-3(2H)-one

Crystal structure of tolylfluanid

Crystal structure of 3-[4-(benzyloxy)phenyl]-2,3-dihydro-1H-benzo[f]chromen-1-one

Crystal structure of 9-(4-bromobutyl)-9H-fluorene-9-carboxylic acid

Crystal structure of 4-(1H-indol-3-yl)-2-(4-methoxyphenyl)-6-phenylpyridine-3-carbonitrile

Crystal structure of ethyl 2-[(4-bromophenyl)amino]-3,4-dimethylpent-3-enoate

Crystal structure of 4-((1E)-1-{(2Z)-2-[4-(4-bromophenyl)-3-phenyl-2,3-dihydro-1,3-thiazol-2-ylidene]hydrazin-1-ylidene}ethyl)phenol hemihydrate

Crystal structure of [(2S)-1-[(3S)-3-carboxy-6,7-dimethoxy-1,2,3,4-tetrahydroisoquinolin-2-yl]-1-oxopropan-2-yl][(2S)-1-ethoxy-1-oxo-4-phenylbutan-2-yl]azanium chloride acetonitrile monosolvate

Crystal structure of 4,5-bis(3,4,5-trimethoxyphenyl)-2H-1,2,3-triazole methanol monosolvate

Crystal structure of 2-bromo-1,4-dihydroxy-9,10-anthraquinone

Crystal structure of 3-methyl-1-phenyl-5-(1H-pyrrol-1-yl)-1H-pyrazole-4-carbaldehyde

Crystal structure of 1,3-bis(4-hexyl-5-iodothiophen-2-yl)-4,5,6,7-tetrahydro-2-benzothiophene

Crystal structure of 3,6-bis(2-chlorophenyl)-1,2,4,5-tetrazine: the acaricide clofentezine

Crystal structure of (4Z)-1-(3,4-dichlorophenyl)-4-[hydroxy(4-methylphenyl)methylidene]-3-methyl-4,5-dihydro-1H-pyrazol-5-one

Crystal structure of bis(4-allyl-2-methoxyphenyl) terephthalate

Crystal structure of 2-bromobenzoic acid at 120 K: a redetermination

Crystal structure of (5R)-5-[(1S)-1,2-dihydroxyethyl]-4-methoxy-3-phenyl-2,5-dihydrofuran-2-one

Crystal structure of triphenyl(vinyl)phosphonium tetraphenylborate

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Crystal structure of (2,11-diaza[3.3](2,6)pyridinophane-κ $^{4}$ N,N′,N′′,N′′′)(1,6,7,12-tetraazaperylene-κ $^{2}$ N $^{1},N$ $^{12})ruthenium(II)$ bis(hexafluoridophosphate) acetonitrile 1.422-solvate

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Brietzke, Thomas Holdt, Hans-jürgen Rottke, Falko Otto Kelling, Alexandra Schilde, Uwe
Description	Author Affiliation: Brietzke T ( Universität Potsdam, Institut für Chemie, Anorganische Chemie, Karl-Liebknecht-Str. 24-25, D-14476 Potsdam, Germany.); Rottke FO ( Universität Potsdam, Institut für Chemie, Anorganische Chemie, Karl-Liebknecht-Str. 24-25, D-14476 Potsdam, Germany.); Kelling A ( Universität Potsdam, Institut für Chemie, Anorganische Chemie, Karl-Liebknecht-Str. 24-25, D-14476 Potsdam, Germany.); Schilde U ( Universität Potsdam, Institut für Chemie, Anorganische Chemie, Karl-Liebknecht-Str. 24-25, D-14476 Potsdam, Germany.); Holdt HJ ( Universität Potsdam, Institut für Chemie, Anorganische Chemie, Karl-Liebknecht-Str. 24-25, D-14476 Potsdam, Germany.)
Abstract	In the title compound, $[Ru(C_{14}H_{16}N_{4})(C_{16}H_{8}N_{4})](PF_{6})_{2}·1.422CH_{3}CN,$ discrete dimers of complex cations, $[Ru(L–N_{4}H_{2})tape]^{2+}$ are formed $\{L–N_{4}H_{2}$ = 2,11-diaza[3.3](2,6)pyridinophane; tape = 1,6,7,12-tetraazaperylene}, held together by π–π stacking interactions via the tape ligand moieties with a centroid–centroid distance of 3.49 (2) Å, assisted by hydrogen bonds between the non-coordinating tape ligand α,α′-diimine unit and the amine proton of a 2,11-diaza[3.3](2,6)-pyridinophane ligand of the opposite complex cation. The combination of these interactions leads to an unusual nearly face-to-face π–π stacking mode. Additional weak C—H⋯N, C—H⋯F, N—H⋯F and P—F⋯π-ring (tape, py) (with F⋯centroid distances of 2.925–3.984 Å) interactions are found, leading to a three-dimensional architecture. The $Ru^{II}$ atom is coordinated in a distorted octahedral geometry, particularly manifested by the $N_{amine}—Ru—N_{amine}$ angle of 153.79 (10)°. The counter-charge is provided by two hexafluoridophosphate anions and the asymmetric unit is completed by acetonitrile solvent molecules of crystallization. Disorder was observed for both the hexafluoridophosphate anions as well as the acetonitrile solvate molecules, with occupancies for the major moieties of 0.801 (6) for one of the $PF_{6}$ anions, and a shared occupancy of 0.9215 (17) for the second $PF_{6}$ anion and a partially occupied acetonitrile molecule. A second $CH_{3}CN$ molecule is fully occupied, but 1:1 disordered across a crystallographic inversion center.
ISSN	20569890
e-ISSN	16005368
Journal	Acta Crystallographica Section E Structure Reports Online
Issue Number	Pt 10
Volume Number	70
Language	English
Publisher	IUCr/Wiley
Publisher Date	2014-10-01
Publisher Place	United States
Access Restriction	Open
Subject Keyword	Crystallography
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics Materials Science

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