NDLI: KNi(0.93)Fe(II)(0.07)Fe(III)(PO4)2: a new type of structure for a compound of composition M(I)M(II)M(III)(PO4)2.

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Year: 2014 Volume: 70 Issue: Part 1

KNi(0.93)Fe(II)(0.07)Fe(III)(PO4)2: a new type of structure for a compound of composition M(I)M(II)M(III)(PO4)2.

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Strutynska, Nataliya Yu Zatovsky, Igor V. Baumer, Vyacheslav N. Ogorodnyk, Ivan V. Slobodyanik, Nikolay S.
Description	Country affiliation: Ukraine Author Affiliation: Strutynska NY ( Department of Inorganic Chemistry, Taras Shevchenko National University, 64/13 Volodymyrska Str., 01601 Kyiv, Ukraine.); Zatovsky IV ( Department of Inorganic Chemistry, Taras Shevchenko National University, 64/13 Volodymyrska Str., 01601 Kyiv, Ukraine.); Baumer VN ( STC `Institute for Single Crystals', NAS of Ukraine, 60 Lenin Ave., 61001 Kharkiv, Ukraine.); Ogorodnyk IV ( Department of Inorganic Chemistry, Taras Shevchenko National University, 64/13 Volodymyrska Str., 01601 Kyiv, Ukraine.); Slobodyanik NS ( Department of Inorganic Chemistry, Taras Shevchenko National University, 64/13 Volodymyrska Str., 01601 Kyiv, Ukraine.)
Abstract	The solid solution KNi(0.93)Fe(II)(0.07)Fe(III)(PO4)2 {potassium [nickel(II)/iron(II)] iron(III) bis(orthophosphate)} has been prepared by the flux method. The compound shows a new type of structure for a phosphate with the general composition M(I)M(II)M(III)(PO4)2. The framework is formed by [(Ni/Fe)O6] polyhedra [Fe site occupancy = 0.069â (14)] linked via shared oxygen vertices forming a cis-like parallel chain stretching along a and [FeO5] polyhedra (located on alternate sides of the chains) connected via two types of PO4 groups into a three-dimensional structure. The K atoms are disordered between two sites, denoted K1A and K1B, with occupancies of 0.930â (9) and 0.070â (9), respectively, and reside inside channels along the a axis. Calculations of the Voronoi-Dirichlet polyhedra of the K atoms give a coordination scheme for K1A of [9â +â 3] and for K1B of [10â +â 2]. The most remarkable feature of the structure is the splitting of the K-atom site and the population of the K1A and K1B positions due to substitution of Ni by Fe in the (Ni/Fe) position.
File Format	HTM / HTML
Issue Number	Pt 2
Journal	Acta Crystallographica Section C Structural Chemistry
Volume Number	70
e-ISSN	20532296
Language	English
Publisher	IUCr
Publisher Date	2014-02-01
Publisher Place	Great Britain (UK)
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Discipline Crystallography Discipline Analytical Chemistry
Content Type	Text
Resource Type	Article

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