NDLI: Mixed-ligand MnII and CuII complexes with alternating 2,2'-bipyrimidine and terephthalate bridges.

Please wait, while we are loading the content...

Year: 2017 Volume: 73

Year: 2016 Volume: 72

Year: 2015 Volume: 71

Year: 2015 Volume: 71 Issue: Part 12

Year: 2015 Volume: 71 Issue: Part 11

Year: 2015 Volume: 71 Issue: Part 10

Year: 2015 Volume: 71 Issue: Part 9

Year: 2015 Volume: 71 Issue: Part 8

Year: 2015 Volume: 71 Issue: Part 7

Year: 2015 Volume: 71 Issue: Part 6

Year: 2015 Volume: 71 Issue: Part 5

Year: 2015 Volume: 71 Issue: Part 4

Year: 2015 Volume: 71 Issue: Part 3

Year: 2015 Volume: 71 Issue: Part 2

The three-component cocrystal 1,3,5-trifluoro-2,4,6-triiodobenzene-pyridine N-oxide-water (1/2/1) built up by halogen bonds, hydrogen bonds and π-π interactions.

Synthesis and crystal structure of 2-amino-3-hydroxypyridinium dioxido(pyridine-2,6-dicarboxylato-κ³O²,N,O6)vanadate(V) and its conversion to nanostructured V2O5.

A new three-dimensional CdII supramolecular framework constructed from the 1-[(1H-tetrazol-5-yl)methyl]-1,4-diazoniabicyclo[2.2.2]octane ligand.

A two-dimensional zincII coordination polymer created via in situ ligand synthesis involving C-N bond formation.

A linear heterometallic bismuth-copper coordination polymer containing two types of organic ligands.

A structural study of 4-aminoantipyrine and six of its Schiff base derivatives.

Mixed-ligand MnII and CuII complexes with alternating 2,2'-bipyrimidine and terephthalate bridges.

Mononuclear and three-dimensional metal complexes based on a multidentate hydrazone ligand.

Two fac-tricarbonylrhenium(I) azadipyrromethene (ADPM) complexes: ligand-substitution effect on crystal structure.

The first polymorph in the family of nucleobases: a second form of cytosine.

A three-dimensional coordination polymer based on the Zn4(µ3-OH)2 unit: poly[[(µ4-benzene-1,4-dicarboxylato)bis(µ3-benzene-1,4-dicarboxylato)bis(µ3-hydroxido)bis(1,10-phenanthroline-5,6-dione)tetrazinc] dihydrate].

Low-dimensional coordination polymeric structures in alkali metal complex salts of the herbicide (2,4-dichlorophenoxy)acetic acid (2,4-D).

Charge-assisted hydrogen bonding in salts of 2-amino-1H-benzimidazole with 3-phenylpropynoic acid and oct-2-ynoic acid.

A two-dimensional copper(II) coordination polymer based on 2-propyl-1H-imidazole-4,5-dicarboxylic acid.

Synthesis and crystal structure of 2-isocyano-4-methylphenyl diphenylacetate: a rare case of an easily accessible odourless isocyanide.

New isostructural transition metal complexes with a non-innocent dithiolate ligand.

Structural and spectropscopic studies of a three-dimensional hydrogen-bonded copper(II) complex: aqua[bis(pyridin-2-ylcarbonyl)amidato]cyanidocopper(II).

Year: 2015 Volume: 71 Issue: Part 1

Year: 2014 Volume: 70

Mixed-ligand MnII and CuII complexes with alternating 2,2'-bipyrimidine and terephthalate bridges.

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Poleti, Dejan Rogan, Jelena Rodic, Marko V. Radovanovic, Lidija
Description	Author Affiliation: Poleti D ( Department of General and Inorganic Chemistry, Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11000 Belgrade, Serbia.); Rogan J ( Department of General and Inorganic Chemistry, Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11000 Belgrade, Serbia.); Rodic MV ( Faculty of Sciences, University of Novi Sad, Trg Dositeja Obradovica 3, 21000 Novi Sad, Serbia.); Radovanovic L ( Innovation Center, Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11000 Belgrade, Serbia.)
Abstract	The novel polymeric complexes catena-poly[[diaquamanganese(II)]-µ-2,2'-bipyrimidine-κ(4)N(1),N(1'):N(3),N(3')-[diaquamanganese(II)]-bis(µ-terephthalato-κ(2)O(1):O(4))], [Mn2(C8H4O4)2(C8H6N4)(H2O)4]n, (I), and catena-poly[[[aquacopper(II)]-µ-aqua-µ-hydroxido-µ-terephthalato-κ(2)O(1):O(1')-copper(II)-µ-aqua-µ-hydroxido-µ-terephthalato-κ(2)O(1):O(1')-[aquacopper(II)]-µ-2,2'-bipyrimidine-κ(4)N(1),N(1'):N(3),N(3')] tetrahydrate], {[Cu3(C8H4O4)2(OH)2(C8H6N4)(H2O)4]·4H2O}n, (II), containing bridging 2,2'-bipyrimidine (bpym) ligands coordinated as bis-chelates, have been prepared via a ligand-exchange reaction. In both cases, quite unusual coordination modes of the terephthalate (tpht(2-)) anions were found. In (I), two tpht(2-) anions acting as bis-monodentate ligands bridge the Mn(II) centres in a parallel fashion. In (II), the tpht(2-) anions act as endo-bridges and connect two Cu(II) centres in combination with additional aqua and hydroxide bridges. In this way, the binuclear [Mn2(tpht)2(bpym)(H2O)4] entity in (I) and the trinuclear [Cu3(tpht)2(OH)2(bpym)(H2O)4]·4H2O coordination entity in (II) build up one-dimensional polymeric chains along the b axis. In (I), the Mn(II) cation lies on a twofold axis, whereas the four central C atoms of the bpym ligand are located on a mirror plane. In (II), the central Cu(II) cation is also on a special position (site symmetry -1). In the crystal structures, the packing of the chains is further strengthened by a system of hydrogen bonds [in both (I) and (II)] and weak face-to-face π-π interactions [in (I)], forming three-dimensional metal-organic frameworks. The Mn(II) cation in (I) has a trigonally deformed octahedral geometry, whereas the Cu(II) cations in (II) are in distorted octahedral environments. The Cu(II) polyhedra are inclined relative to each other and share common edges.
File Format	HTM / HTML
Issue Number	Pt 2
Volume Number	71
e-ISSN	20532296
Journal	Acta Crystallographica Section C Structural Chemistry
Language	English
Publisher	IUCr
Publisher Date	2015-02-01
Publisher Place	Great Britain (UK)
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Discipline Crystallography Discipline Analytical Chemistry Coordination Complexes Chemistry Copper Manganese Phthalic Acids Pyrimidines Chelating Agents Crystallography, X-ray Hydrogen Bonding Ligands Journal Article Research Support, Non-u.s. Gov't
Content Type	Text
Resource Type	Article

Central Library (ISO-9001:2015 Certified)
Indian Institute of Technology Kharagpur
Kharagpur, West Bengal, India | PIN - 721302

See location in the Map
03222 282435
Mail: support@ndl.gov.in

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in