NDLI: A three-dimensional metal-organic polymer: poly[bis(µ2-pyrimidine-2-thiolato-κ4N¹,S:S,N³)lead(II)].

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A three-dimensional metal-organic polymer: poly[bis(µ2-pyrimidine-2-thiolato-κ4N¹,S:S,N³)lead(II)].

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A three-dimensional metal-organic polymer: poly[bis(µ2-pyrimidine-2-thiolato-κ4N¹,S:S,N³)lead(II)].

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Schwade, Vania Denise Lang, Ernesto Schulz Floriano, Luana
Description	Country affiliation: Brazil Author Affiliation: Schwade VD ( Faculdade de Ciências Exatas e Tecnologia, Universidade Federal da Grande Dourados, Rodovia Dourados-Itahum, km 12, Dourados-MS 79804-970, Brazil.); Lang ES ( Departamento de Química, Universidade Federal de Santa Maria, Avenida Roraima, 1000, Camobi, Santa Maria-RS 97105-900, Brazil.); Floriano L ( Departamento de Química, Universidade Federal de Santa Maria, Avenida Roraima, 1000, Camobi, Santa Maria-RS 97105-900, Brazil.)
Abstract	The title compound, [Pb(C4H3N2S)2]n, was prepared by the reaction of [Pb(OAc)2]·3H2O (OAc is acetate) with pyrimidine-2-thione in the presence of triethylamine in methanol. In the crystal structure, the Pb(II) atom has an N4S4 coordination environment with four ligands coordinated by N- and S-donor atoms. This compound shows that the pyrimidine-2-thiolate anion can lead to a three-dimensional network when the coordination number of the metal ion can be higher than 6, as is the case with the Pb(II) ion. This compound presents only covalent bonds, showing that despite the possibility of the hemidirected geometries of Pb(II), the eight-coordinated ion does not allow the formation of an isolated molecular structure with pyrimidine-2-thiolate as the ligand.
File Format	HTM / HTML
Issue Number	Pt 7
Volume Number	71
e-ISSN	20532296
Journal	Acta Crystallographica Section C Structural Chemistry
Language	English
Publisher	IUCr
Publisher Date	2015-07-01
Publisher Place	Great Britain (UK)
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Discipline Crystallography Discipline Analytical Chemistry Coordination Complexes Chemistry Organometallic Compounds Pyrimidines Sulfhydryl Compounds Crystallography, X-ray Hydrogen Bonding Ligands Molecular Structure Journal Article Research Support, Non-u.s. Gov't
Content Type	Text
Resource Type	Article

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