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| Content Provider | World Health Organization (WHO)-Global Index Medicus |
|---|---|
| Author | Ma, Yan Russell, Andrew T. Marston, George |
| Description | Author Affiliation: Ma Y ( Department of Chemistry, Reading University, Whiteknights, PO Box 224, Reading, UK RG6 6AD.) |
| Abstract | Gas-phase ozonolysis of alpha-pinene was studied in static chamber experiments under 'OH-free' conditions. A range of multifunctional products-in particular low-volatility carboxylic acids-were identified in the condensed phase using gas chromatography coupled to mass spectrometry after derivatisation. The dependence of product yields on reaction conditions (humidity, choice of OH radical scavengers, added Criegee intermediate scavengers, NO(2)etc.) was investigated to probe the mechanisms of formation of these products; additional information was obtained by studying the ozonolysis of an enal and an enone derived from alpha-pinene. On the basis of experimental findings, previously suggested mechanisms were evaluated and detailed gas-phase mechanisms were developed to explain the observed product formation. Atmospheric implications of this work are discussed. |
| File Format | HTM / HTML |
| ISSN | 14639076 |
| Issue Number | 29 |
| Volume Number | 10 |
| e-ISSN | 14639084 |
| Journal | Physical Chemistry Chemical Physics |
| Language | English |
| Publisher | Royal Society of Chemistry |
| Publisher Date | 2008-08-07 |
| Publisher Place | Great Britain (UK) |
| Access Restriction | Subscribed |
| Subject Keyword | Discipline Physics Discipline Biophysics Discipline Chemistry Gases Chemistry Monoterpenes Ozone Aerosols Free Radical Scavengers Hydroxyl Radical Nitrogen Dioxide Journal Article Research Support, Non-u.s. Gov't |
| Content Type | Text |
| Resource Type | Article |
| Subject | Physics and Astronomy Physical and Theoretical Chemistry |
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