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| Content Provider | World Health Organization (WHO)-Global Index Medicus |
|---|---|
| Author | Cohen, Elizabeth L. Patterson, Bradley M. McKinley, Allan J. Prommer, Henning |
| Description | Country affiliation: Australia Author Affiliation: Cohen EL ( CSIRO Land and Water, Private Bag No. 5, Wembley WA 6913, Australia.) |
| Abstract | The suitability of a granulated zero valent iron (ZVI) permeable reactive barrier (PRB) remediation strategy was investigated for tribromoethene (TriBE), cis-1,2-dibromoethene (c-DBE), trans-1,2-dibromoethene (t-DBE) and vinyl bromide (VB), via batch and large-scale column experiments that were subsequently analysed by reactive transport modelling. The brominated ethenes in both batch and large-scale column experiments showed rapid (compared to controls and natural attenuation) degradation in the presence of ZVI. In the large-scale column experiment, degradation half-lives were 0.35 days for TriBE, 0.50 days for c-DBE, 0.31 days for t-DBE and 0.40 days for VB, under site groundwater flow conditions, resulting in removal of brominated ethenes within the first 0.2 m of a 1.0 m thick ZVI layer, indicating that a PRB groundwater remediation strategy using ZVI could be used successfully. In the model simulations of the ZVI induced brominated ethene degradation, assuming a dominant reductive beta-elimination pathway via bromoacetylene and acetylene production, simulated organic compound concentrations corresponded well with both batch and large-scale column experimental data. Changes of inorganic reactants were also well captured by the simulations. The similar ZVI induced degradation pathway of TriBE and TCE suggests that outcomes from research on ZVI induced TCE remediation could also be applied to TriBE remediation. |
| File Format | HTM / HTML |
| ISSN | 01697722 |
| Issue Number | 3-4 |
| Volume Number | 103 |
| e-ISSN | 18736009 |
| Journal | Journal of Contaminant Hydrology |
| Language | English |
| Publisher | Elsevier |
| Publisher Date | 2009-01-26 |
| Publisher Place | Netherlands |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Discipline Chemistry Discipline Toxicology Bromine Compounds Analysis Chemistry Environmental Restoration And Remediation Ethylenes Fresh Water Iron Water Pollutants, Chemical Calibration Microscopy, Electron, Scanning Models, Chemical Molecular Structure Journal Article Research Support, Non-u.s. Gov't |
| Content Type | Text |
| Resource Type | Article |
| Subject | Environmental Chemistry Water Science and Technology |
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