NDLI: Rapid preparation of flexible porous coordination polymer nanocrystals with accelerated guest adsorption kinetics.

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Rapid preparation of flexible porous coordination polymer nanocrystals with accelerated guest adsorption kinetics.

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Tanaka, Daisuke Henke, Artur Albrecht, Krystyna Moeller, Martin Nakagawa, Keiji Kitagawa, Susumu Groll, Juergen
Description	Country affiliation: Germany Author Affiliation: Tanaka D ( Institute of Technical and Macromolecular Chemistry, RWTH Aachen University, Pauwelsstrasse 8, 52056 Aachen, Germany.)
Abstract	Porous coordination polymers, in particular flexible porous coordination polymer networks that change their network structure on guest adsorption, have enormous potential in applications involving selective storage, separation and sensing. Despite the expected significant differences in their adsorption properties, porous coordination polymer nanocrystals remain largely unexplored, and there have been no reports about studies on flexible porous coordination polymer nanocrystals, mainly due to a lack of preparation methods. Here, we present a new technique for the rapid preparation of porous coordination polymer nanocrystals that combines non-aqueous inverse microemulsion with ultrasonication. Uniform nanocrystals of {[Zn(ip)(bpy)]}(n) (ip = isophthalate, bpy = 4,4'-bipyridyl; CID-1), a flexible porous coordination polymer, have been prepared by this method and analysed using field-emission scanning electron microscopy, energy-dispersive X-ray analysis, infrared spectroscopy, Raman spectroscopy and X-ray powder diffraction. A model for particle formation and growth is presented and discussed. Adsorption experiments with methanol show that the overall adsorption capacities of nanoparticles and bulk are almost identical, but the shapes of the sorption isotherms differ significantly and the adsorption kinetics increase dramatically.
File Format	HTM / HTML
ISSN	17554330
Issue Number	5
Volume Number	2
e-ISSN	17554349
Journal	Nature Chemistry
Language	English
Publisher	Nature Publishing Group
Publisher Date	2010-05-01
Publisher Place	Great Britain (UK)
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Discipline Chemistry Coordination Complexes Chemistry Nanoparticles Polymers Adsorption Kinetics Microscopy, Electron, Scanning Ultrastructure Porosity Time Factors Journal Article Research Support, Non-u.s. Gov't
Content Type	Text
Resource Type	Article
Subject	Chemistry Chemical Engineering

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