NDLI: Degradation of chlorobenzene by Fenton‐like processes using zero‐valent iron in the presence of $Fe^{3+}$ and $Cu^{2+}$

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Degradation of chlorobenzene by Fenton‐like processes using zero‐valent iron in the presence of $Fe^{3+}$ and $Cu^{2+}$

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Pagano, Michele Volpe, Angela Lopez, Antonio Mascolo, Giuseppe Ciannarella, Ruggiero
Description	Country affiliation: Italy Author Affiliation: Pagano M ( Consiglio Nazionale delle Ricerche, Istituto di Ricerca Sulle Acque, Sezione di Bari, Via Francesco De Blasio 5, Bari 70123, Italy.)
Abstract	Batch and column tests were conducted to compare the efficiencies of three Fenton‐like systems in the degradation of chlorobenzene. In the investigated systems, iron powder was the source of $Fe^{2+}$ ions, and either $Fe^{3+}$ or $Cu^{2+}$ were added in order to enhance the degradation process. Optimum pH and concentrations of $Fe^{3+},$ $Cu^{2+}$ and hydrogen peroxide were assessed by treating synthetic chlorobenzene solutions both in batch and in column mode, thus achieving the minimum residual concentration of chlorobenzene. Optimum conditions assessed by means of column tests were then applied to column treatment of real chlorobenzene‐contaminated groundwater. Results showed that, when the TOC content of water was above 12 mg $L^{−1},$ the performance of the $Fe^{0}/H_{2}O_{2}$ system was enhanced by the addition of $Fe^{3+},$ leading to 10–20 µg $L^{−1}$ of residual chlorobenzene.
File Format	HTM / HTML
ISSN	09593330
Issue Number	1-2
Volume Number	32
e-ISSN	1479487X
Journal	Environmental Technology
Language	English
Publisher	Taylor & Francis
Publisher Date	2011-01-01
Publisher Place	Great Britain (UK)
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Discipline Environmental Health Chlorobenzenes Chemistry Copper Iron Water Pollutants, Chemical Water Purification Methods Analysis Chlorophenols Hydrogen Peroxide Hydrogen-ion Concentration Oxidation-reduction Journal Article Research Support, Non-u.s. Gov't
Content Type	Text
Resource Type	Article
Subject	Environmental Chemistry Waste Management and Disposal Medicine Water Science and Technology

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Degradation of chlorobenzene by Fenton‐like processes using zero‐valent iron in the presence of $Fe^{3+}$ and $Cu^{2+}$

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Degradation of chlorobenzene by Fenton‐like processes using zero‐valent iron in the presence of $Fe^{3+}$ and $Cu^{2+}$