NDLI: A bis(amine-carboxylate) copper(II) coordination compound forms a two-dimensional metal-organic framework when crystallized from water and methanol

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A bis(amine-carboxylate) copper(II) coordination compound forms a two-dimensional metal-organic framework when crystallized from water and methanol

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A bis(amine-carboxylate) copper(II) coordination compound forms a two-dimensional metal-organic framework when crystallized from water and methanol

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Munro, Orde Q. Akerman, Matthew P. Gillham, Kate
Description	Country affiliation: South Africa Author Affiliation: Munro OQ ( School of Chemistry, University of KwaZulu-Natal, Private Bag X01, Scottsville 3209, South Africa. munroo@ukzn.ac.za)
Abstract	When {2,2'-[(2-methyl-2-nitropropane-1,3-diyl)diimino]diacetato}copper(II), [Cu(C $_{8}H$ $_{13}N$ $_{3}O$ $_{6})],$ (I), was crystallized from a binary mixture of methanol and water, a monoclinic two-dimensional water- and methanol-solvated metal-organic framework (MOF) structure, distinctly different from the known orthorhombic one-dimensional coordination polymer of (I), was isolated, namely catena-poly[[copper(II)- $_{3}-2,2`-[(2-methyl-2-nitropropane-1,3-diyl)diimino]diacetato]$ methanol 0.45-solvate 0.55-hydrate], {[Cu(C $_{8}H$ $_{13}N$ $_{3}O$ $_{6})]·0.45CH$ $_{3}OH·0.55H$ $_{2}O}$ $_{n},$ (II). The monoclinic structure of (II) comprises centrosymmetric dimers stabilized by a dative covalent Cu $_{2}O$ $_{2}$ core and intramolecular N-H O hydrogen bonds. Each dimer is linked to four neighbouring dimers via symmetry-related (opposing) pairs of bridging carboxylate O atoms to generate a `diamondoid' net or two-dimensional coordination network. Tight voids of 166 Å $^{3}$ are located between these two-dimensional MOF sheets and contain a mixture of water and methanol with fractional occupancies of 0.55 and 0.45, respectively. The two-dimensional MOF sheets have nanometre-scale spacings (11.2 Å) in the crystal structure. Hydrogen-bonding between the methanol/water hydroxy groups and a Cu-bound bridging carboxylate O atom apparently negates thermal desolvation of the structure below 358 K in an uncrushed crystal of (II).
File Format	HTM / HTML
e-ISSN	20532296
Journal	Acta Crystallographica Section C Crystal Structure Communications
Issue Number	Pt 9
Volume Number	65
Language	English
Publisher	IUCr/Wiley
Publisher Date	2009-09-01
Publisher Place	United States
Access Restriction	Open
Subject Keyword	Discipline Analytical Chemistry Discipline Crystallography Copper Chemistry Organometallic Compounds Crystallization Crystallography, X-ray Hydrogen Bonding Methanol Models, Molecular Research Support, Non-u.s. Gov't
Content Type	Text
Resource Type	Article

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