NDLI: Coulombic interactions, hydrogen bonding and supramolecular chirality in pyridinium trifluoromethanesulfonate

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Goldberg, Israel
Description	Country affiliation: Israel Author Affiliation: Goldberg I ( School of Chemistry, Sackler Faculty of Exact Sciences, Tel-Aviv University, Ramat-Aviv, 69978 Tel-Aviv, Israel. goldberg@post.tau.ac.il)
Abstract	The title compound, C $_{5}H$ $_{6}N$ $^{+}·CF$ $_{3}SO$ $_{3}$ $^{-},$ was serendipitously crystallized in the chiral space group P4 $_{3}2$ $_{1}2.$ The component entities associate into hydrogen-bonded helical chains, which propagate along the a and b axes of the crystal, with an alternating disposition of the cations and anions along the chain. N-H O charge-assisted hydrogen bonds, from each pyridinium cation to two adjacent trifluoromethanesulfonate anions and from every anion to two different cations, direct the formation of the supramolecular chiral arrays. The crystal packing exhibits nonconventional C-H O and C-H F hydrogen bonds between the components. The observed structure demonstrates induction of supramolecular chirality by a combination of Coulombic attractions and intermolecular hydrogen bonds.
File Format	HTM / HTML
e-ISSN	20532296
Journal	Acta Crystallographica Section C Crystal Structure Communications
Issue Number	Pt 10
Volume Number	65
Language	English
Publisher	IUCr/Wiley
Publisher Date	2009-10-01
Publisher Place	United States
Access Restriction	Open
Subject Keyword	Discipline Analytical Chemistry Discipline Crystallography
Content Type	Text
Resource Type	Article

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Coulombic interactions, hydrogen bonding and supramolecular chirality in pyridinium trifluoromethanesulfonate