NDLI: Crystallographic evidence of Gly-D,L-Met oxidation to its sulfoxide in the presence of gold(III): solid solution of the racemic mixture of two diastereoisomers

Please wait, while we are loading the content...

Two caesium vanadium hydrogenphosphates with tunnelled structures: $Cs_{2}V_{2}O_{3}(PO_{4})(HPO_{4})$ and $Cs_{2}[(VO)_{3}(HPO_{4})_{4}(H_{2}O)]·H_{2}O$

$K_{3}TaF_{8}$ from laboratory X-ray powder data

$(H_{3}O)Nd(SO_{4})_{2}$

catena-Poly[bis(trimethylphenylammonium) [hexa--chlorido-dichloridotricuprate(II)]]: an alternating zigzag chain of $CuCl_{4}$ and $Cu_{2}Cl_{6}$ complexes

A tetrazol-5-yl analogue of glycine, 5-ammoniomethyl-1H-tetrazolide, and its copper(II) complex

$Poly[_{8}-4,4`-bipyridine-2,2`,6,6`-tetracarboxylato-dilead(II)]$

$Poly[[trans-diaquabis(_{2}-biphenyl-2,2`-dicarboxylato)bis(_{2}-4,4`-bipyridine)dicobalt(II)]$ biphenyl-2,2'-dicarboxylic acid disolvate]

Luminescence properties of the structure built from 3-cyano-4-dicyanomethylene-5-oxo-4,5-dihydro-1H-pyrrol-2-olate and caesium(I)

Granisetron, an antiemetic drug, and its cobalt complex

Tris(tert-butyl isocyanide)bis[tris(4-methoxyphenyl)phosphine]cobalt(I) perchlorate dichloromethane disolvate and tris(tert-butyl isocyanide)bis[tris(4-methoxyphenyl)phosphine]cobalt(II) bis(perchlorate) dichloromethane disolvate: modification of a trigonal-bipyramidal structure with change of metal oxidation state

Two polymorphs of a lead(II) complex with 8-hydroxy-2-methylquinoline and thiocyanate

$Triaqua(-7-iodo-8-oxidoquinoline-5-sulfonato-^{2}N,O^{8})dioxidouranium(VI)$ dihydrate

Crystallographic evidence of Gly-D,L-Met oxidation to its sulfoxide in the presence of gold(III): solid solution of the racemic mixture of two diastereoisomers

Modulating the preferred O-HO hydrogen-bonding motif in a conformationally constrained environment through hydroxy-group derivatization

N-(3-tert-Butyl-1-phenyl-1H-pyrazol-5-yl)-N-(4-methoxybenzyl)acetamide: a hydrogen-bonded chain of centrosymmetric rings

Methyl 4-O--D-galactopyranosyl -D-mannopyranoside methanol 0.375-solvate

Seven 3-methylidene-1H-indol-2(3H)-ones related to the multiple-receptor tyrosine kinase inhibitor sunitinib

Hydrogen-bonding patterns in 3-alkyl-3-hydroxyindolin-2-ones

4-(9,10-Dihydroacridin-9-ylidene)thiosemicarbazide and its five-membered thiazole and six-membered thiazine derivatives

Two concomitant polymorphs of N,N'-bis[4-(diethylamino)phenyl]terephthaldiamide

Clindamycin hydrochloride monohydrate and its ethanol solvate

Year: 2010 Volume: 66 Issue: Part 1

Year: 2009 Volume: 65

Year: 2008 Volume: 64

Crystallographic evidence of Gly-D,L-Met oxidation to its sulfoxide in the presence of gold(III): solid solution of the racemic mixture of two diastereoisomers

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Rychlewska, Urszula Warzajtis, Beata Glisic, Biljana D. Rajkovic, Snezana Djuran, Milos
Description	Country affiliation: Poland Author Affiliation: Rychlewska U ( Department of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780 Poznan, Poland. urszular@amu.edu.pl)
Abstract	Crystallographic analysis of a solid solution of two diastereoisomers, i.e. ({(1 S, R)-1-carboxy-3-[( R, S)-methylsulfinyl]propyl}aminocarbonyl)methanaminium tetrachloridoaurate(III) and ({(1 S, R)-1-carboxy-3-[( S, R)-methylsulfinyl]propyl}aminocarbonyl)methanaminium tetrachloridoaurate(III), (C $_{7}H$ $_{15}N$ $_{2}O$ $_{4}S)[AuCl$ $_{4}],$ has shown that in the presence of gold(III), the methionine part of the Gly- D, L-Met dipeptide is oxidized to sulfoxide, and no coordination to the Au $^{III}$ cation through the S atom of the sulfoxide is observed. In view of our observation, literature reports that methionine acts as an N, S-bidentate donor ligand forming stable gold(III) complexes require verification. Moreover, it has been demonstrated that crystallization of the oxidation product leads to a substantial 77:23 excess of both S-methionine/ R-sulfoxide and R-methionine/ S-sulfoxide over S-methionine/ S-sulfoxide and R-methionine/ R-sulfoxide. The presence of two different diastereoisomers at the same crystallographic site is a source of static disorder at this site.
File Format	HTM / HTML
e-ISSN	20532296
Journal	Acta Crystallographica Section C Crystal Structure Communications
Issue Number	Pt 2
Volume Number	66
Language	English
Publisher	IUCr/Wiley
Publisher Date	2010-02-01
Publisher Place	United States
Access Restriction	Open
Subject Keyword	Discipline Analytical Chemistry Discipline Crystallography Dipeptides Chemistry Safrole Analogs & Derivatives Crystallography, X-ray Isomerism Models, Molecular Oxidation-reduction Research Support, Non-u.s. Gov't
Content Type	Text
Resource Type	Article

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

A comparative study of complex formation in the reactions of gold(III) with Gly-Gly, Gly-L-Ala and Gly-L-His dipeptides.

Comparison of racemic epi-inosose and (-)-epi-inosose

The hydrated and anhydrous gold(III) tetrachloride salts of L-ecgonine, an important forensic toxicology marker for cocaine

Oxidation of allyl alcohol in the presence of a gold catalyst: a route to 3-hydroxypropionic acid.

An unexpected tetragonal unit cell for N-(L-2-aminobutyryl)-L-serine

N-(L-2-Aminopentanoyl)-L-phenylalanine dihydrate, a hydrophobic dipeptide with a nonproteinogenic residue

Zwitterionic dithiocarboxylates derived from N-heterocyclic carbenes: coordination to gold surfaces.

Total synthesis of ouabagenin and ouabain.

Air oxidation of a manganese(III) thioether chelate affords the first manganese(III) dihydrosalen complex with a pendant sulfoxide ligand

Crystallographic evidence of Gly-D,L-Met oxidation to its sulfoxide in the presence of gold(III): solid solution of the racemic mixture of two diastereoisomers

Similar Documents

A comparative study of complex formation in the reactions of gold(III) with Gly-Gly, Gly-L-Ala and Gly-L-His dipeptides.

Comparison of racemic epi-inosose and (-)-epi-inosose

The hydrated and anhydrous gold(III) tetra­chloride salts of L-ecgonine, an important forensic toxicology marker for cocaine

Oxidation of allyl alcohol in the presence of a gold catalyst: a route to 3-hydroxypropionic acid.

An unexpected tetra­gonal unit cell for N-(L-2-amino­butyr­yl)-L-serine

N-(L-2-Amino­penta­noyl)-L-phenyl­alanine dihydrate, a hydro­phobic dipeptide with a nonproteinogenic residue

Zwitterionic dithiocarboxylates derived from N-heterocyclic carbenes: coordination to gold surfaces.

Total synthesis of ouabagenin and ouabain.

Air oxidation of a manganese(III) thioether chelate affords the first manganese(III) dihydrosalen complex with a pendant sulfoxide ligand

Crystallographic evidence of Gly-D,L-Met oxidation to its sulfoxide in the presence of gold(III): solid solution of the racemic mixture of two diastereo­isomers

The hydrated and anhydrous gold(III) tetrachloride salts of L-ecgonine, an important forensic toxicology marker for cocaine

An unexpected tetragonal unit cell for N-(L-2-aminobutyryl)-L-serine

N-(L-2-Aminopentanoyl)-L-phenylalanine dihydrate, a hydrophobic dipeptide with a nonproteinogenic residue

Crystallographic evidence of Gly-D,L-Met oxidation to its sulfoxide in the presence of gold(III): solid solution of the racemic mixture of two diastereoisomers