NDLI: $Poly[[[aqua(2,2`-bipyridine-^{2}N,N`)manganese(II)]--croconato-^{4}O,O`:O``,O```]$ monohydrate]: a one-dimensional coordination polymer connected by hydrophilic-hydrophilic and lipophilic-lipophilic interactions at 135 K

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$Poly[[[aqua(2,2`-bipyridine-^{2}N,N`)manganese(II)]--croconato-^{4}O,O`:O``,O```]$ monohydrate]: a one-dimensional coordination polymer connected by hydrophilic-hydrophilic and lipophilic-lipophilic interactions at 135 K

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Year: 2010 Volume: 66 Issue: Part 3

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$Poly[[[aqua(2,2`-bipyridine-^{2}N,N`)manganese(II)]--croconato-^{4}O,O`:O``,O```]$ monohydrate]: a one-dimensional coordination polymer connected by hydrophilic-hydrophilic and lipophilic-lipophilic interactions at 135 K

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Chen, Hong-Feng Fang, Qi Chen, Hong-Yu Yu, Wen-Tao Weng, Lin-Hong
Description	Author Affiliation: Chen HF ( State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, Shandong Province, People's Republic of China.)
Abstract	In the title one-dimensional coordination polymer, {[Mn(C $_{5}O$ $_{5})(C$ $_{10}H$ $_{8}N$ $_{2})(H$ $_{2}O)]·H$ $_{2}O}$ $_{n},$ each Mn $^{II}$ ion is seven-coordinated by four O atoms from two croconate ligands, two N atoms from a 2,2'-bipyridine (2,2'-bipy) ligand and one O atom from an aqua ligand. The croconate ligand bridges the Mn $^{II}$ ions in a bis-bidentate chelation mode, forming an extended [Mn(C $_{5}O$ $_{5})]$ $_{n}$ chain running parallel to the [001] direction, with the lipophilic 2,2'-bipy ligands lying along one side and the hydrophilic water molecules along the opposite side. Coordinated water and solvent water molecules are arranged in the hydrophilic layer, which is characterized by O-H O hydrogen bonds between croconate ligands. Meanwhile, 2,2'-bipy ligands from adjacent chains partially overlap and exhibit - interactions to form a lipophilic layer. The hydrophilic and lipophilic layers are arranged alternately to build a layer structure.
File Format	HTM / HTML
e-ISSN	20532296
Journal	Acta Crystallographica Section C Crystal Structure Communications
Issue Number	Pt 4
Volume Number	66
Language	English
Publisher	IUCr/Wiley
Publisher Date	2010-04-01
Publisher Place	United States
Access Restriction	Open
Subject Keyword	Discipline Analytical Chemistry Discipline Crystallography Manganese Chemistry Organometallic Compounds Polymers Crystallography, X-ray Hydrogen Bonding Ligands Molecular Structure Research Support, Non-u.s. Gov't
Content Type	Text
Resource Type	Article

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