NDLI: The hydrogen-bonded dimers of N,N',N''-tricyclohexylphosphoric triamide in new tin(IV) and copper(II) complexes

Please wait, while we are loading the content...

Year: 2013 Volume: 69

Year: 2012 Volume: 68

Year: 2011 Volume: 67

Year: 2011 Volume: 67 Issue: Part 12

Year: 2011 Volume: 67 Issue: Part 11

Year: 2011 Volume: 67 Issue: Part 10

Year: 2011 Volume: 67 Issue: Part 9

Year: 2011 Volume: 67 Issue: Part 8

Year: 2011 Volume: 67 Issue: Part 7

Year: 2011 Volume: 67 Issue: Part 6

Year: 2011 Volume: 67 Issue: Part 5

$Dy_{2}(SO_{3})_{2}(SO_{4})(H_{2}O)_{2}:$ the first lanthanide mixed sulfate-sulfite inorganic compound

Synthetic ferric sulfate trihydrate, $Fe_{2}(SO_{4})_{3}·3H_{2}O,$ a new ferric sulfate salt

A sodium salt of the dimer of boronoterephthalic acid anhydride

Bis(4-methylbenzylammonium) tetrachloridozincate: a new noncentrosymmetric structure characterized by $^{13}C$ CP-MAS NMR spectroscopy

-Acetato--aqua--hydroxido-bis[(1,10-phenanthroline)copper(II)] dinitrate monohydrate

Diammonium hexakis(thiocyanato-N)rhenate(IV) dimethyl sulfone tetrasolvate

A novel two-dimensional (4,4) network based on dinuclear cadmium secondary building units: $poly[(_{5}-benzene-1,4-diacetato)[_{2}-1,4-bis(1,2,4-triazol-1-yl)butane]cadmium(II)]$

Bis[(dihydrogen $pyrophosphato-^{2}O,O`)(2,2`:6`,2``-terpyridine-^{3}N,N`,N``)copper(II)]$ 4.5-hydrate

$Poly[tetra-_{2}-L-lactato-indium(III)sodium(I)]$

Two polymorphs of tetraethylammonium [hydrogen $tris(3,5-dimethylpyrazolyl)borato]di-_{2}-sulfido-disulfido(^{2}-tetrasulfido)ditungsten(V)$ with Z' = 1 and 2

trans-Dichloridobis(4,8-dimethyl-2-phenyl-2-phosphabicyclo[3.3.1]nonane-P)platinum(II)

A new double-cube nitride complex containing titanium and potassium

The hydrogen-bonded dimers of N,N',N''-tricyclohexylphosphoric triamide in new tin(IV) and copper(II) complexes

trans-Carbonylchloridobis(ferrocenyldiphenylphosphane-P)rhodium(I) dichloromethane monosolvate and trans-carbonylchloridobis(ferrocenyldiphenylphosphane-P)iridium(I) dichloromethane monosolvate

Two isomorphous transition metal complexes containing a protonated diaminopurine ligand: $diaquabis(2,6-diamino-7H-purin-1-ium-N^{9})bis(homophthalato-O)nickel(II)$ tetrahydrate and the cobalt(II) analogue

Multiple intramolecular hydrogen bonds in 2,4-di-tert-butyl-6-[N-(2,6-diisopropylphenyl)-P,P-diphenylphosphorimidoyl]phenol

The effect of Cl interactions on the conformations of 4-chloro-5-(2-phenoxyethoxy)phthalonitrile and 4-chloro-5-[2-(pentafluorophenoxy)ethoxy]phthalonitrile

(2R*,4S*)-2-(Pyridin-3-yl)-2,3,4,5-tetrahydro-1H-1-benzazepin-4-ol: a three-dimensional framework built from O-HN, C-HO and C-H(arene) hydrogen bonds

Acidic and anionic forms of 1,3-cyclic dihydroxyacetone phosphate (cDHAP) dimethyl acetal

2-(Benzoylsulfanyl)acetic acid and 2,5-dioxopyrrolidin-1-yl 2-(benzoylsulfanyl)acetate by powder X-ray diffraction studies

Conformational polymorphism of (E,E)-N,N'-bis(4-nitrobenzylidene)benzene-1,4-diamine

A novel Janus-type AT nucleoside with benzoyl protecting groups forming a pleated-sheet structure

Pseudopolymorphs of 2,6-diaminopyrimidin-4-one and 2-amino-6-methylpyrimidin-4-one: one or two tautomers present in the same crystal

(R)-4-(4-Aminophenyl)-2,2,4-trimethylchroman and (S)-4-(4-aminophenyl)-2,2,4-trimethylthiachroman

Supramolecular patterns in benzyladeninium p-toluenesulfonate

Year: 2011 Volume: 67 Issue: Part 4

Year: 2011 Volume: 67 Issue: Part 3

Year: 2011 Volume: 67 Issue: Part 2

Year: 2011 Volume: 67 Issue: Part 1

Year: 2010 Volume: 66

Year: 2009 Volume: 65

Year: 2008 Volume: 64

The hydrogen-bonded dimers of N,N',N''-tricyclohexylphosphoric triamide in new tin(IV) and copper(II) complexes

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Pourayoubi, Mehrdad Golen, James A. Chaijan, Mahnaz Rostami Divjakovic, Vladimir Negari, Monireh Rheingold, Arnold L.
Description	Country affiliation: Iran Author Affiliation: Pourayoubi M ( Department of Chemistry, Ferdowsi University of Mashhad, Mashhad 91779, Iran. mehrdad_pourayoubi@yahoo.com)
Abstract	In the new tin(IV) and copper(II) complexes, cis-dichlorido- trans-dimethyl- cis-bis( N, N', N''-tricyclohexylphosphoric triamide- O)tin(IV), [Sn(CH $_{3})$ $_{2}Cl$ $_{2}(C$ $_{18}H$ $_{36}N$ $_{3}OP)$ $_{2}],$ (I), and trans-diaquabis( N, N', N''-tricyclohexylphosphoric triamide- O)copper(II) dinitrate- N, N', N''-tricyclohexylphosphoric triamide (1/2), [Cu(C $_{18}H$ $_{36}N$ $_{3}OP)$ $_{2}(H$ $_{2}O)$ $_{2}](NO$ $_{3})$ $_{2}·2C$ $_{18}H$ $_{36}N$ $_{3}OP,$ (II), the N, N', N''-tricyclohexylphosphoric triamide (PTA) ligands exist as hydrogen-bonded dimers via P=O H-N interactions around the metal center. The asymmetric unit in (I) consists of one complete complex molecule located on a general position. The Sn $^{IV}$ coordination geometry is octahedral with two cis hydrogen-bonded PTA ligands, two cis chloride ligands and two trans methyl groups. The asymmetric unit in (II) contains one half of a [Cu(PTA) $_{2}(H$ $_{2}O)$ $_{2}]$ $^{2+}$ dication on a special position (site symmetry for the Cu atom), one nitrate anion and one free PTA molecule, both on general positions. The complex adopts a square-planar trans-[CuO $_{2}O$ $_{2}]$ coordination geometry, with the Cu $^{II}$ ion coordinated by two PTA ligands and two water molecules. Each of the noncoordinated PTA molecules is hydrogen bonded to a neighboring coordinated PTA molecule and an adjacent water molecule; the phosphoryl O atom acts as a double-H-atom acceptor. The P atoms in the PTA ligands of both complexes and in the noncoordinated hydrogen-bonded molecules in (II) adopt a slightly distorted tetrahedral environment.
File Format	HTM / HTML
e-ISSN	20532296
Journal	Acta Crystallographica Section C Crystal Structure Communications
Issue Number	Pt 5
Volume Number	67
Language	English
Publisher	IUCr/Wiley
Publisher Date	2011-05-01
Publisher Place	United States
Access Restriction	Open
Subject Keyword	Discipline Analytical Chemistry Discipline Crystallography
Content Type	Text
Resource Type	Article

Central Library (ISO-9001:2015 Certified)
Indian Institute of Technology Kharagpur
Kharagpur, West Bengal, India | PIN - 721302

See location in the Map
03222 282435
Mail: support@ndl.gov.in

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in