NDLI: $[CuCl_{3}(H_{2}O)]^{-}$ complexes aggregated to form hydrate columns in methyl-substituted pyridinium or piperidinium salts

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$[CuCl_{3}(H_{2}O)]^{-}$ complexes aggregated to form hydrate columns in methyl-substituted pyridinium or piperidinium salts

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$[CuCl_{3}(H_{2}O)]^{-}$ complexes aggregated to form hydrate columns in methyl-substituted pyridinium or piperidinium salts

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Nalla, Sowjanya Bond, Marcus R.
Description	Country affiliation: United States Author Affiliation: Nalla S ( Department of Chemistry, Southeast Missouri State University, Cape Girardeau, MO 63701, USA.)
Abstract	1,2,3-Trimethylpyridinium aquatrichloridocuprate(II), (C $_{8}H$ $_{12}N)[CuCl$ $_{3}(H$ $_{2}O)],$ (I), 3,4-dimethylpyridinium aquatrichloridocuprate(II), (C $_{7}H$ $_{10}N)[CuCl$ $_{3}(H$ $_{2}O)],$ (II), and 2,3-dimethylpyridinium aquatrichloridocuprate(II), (C $_{7}H$ $_{10}N)[CuCl$ $_{3}(H$ $_{2}O)],$ (III), exhibit the same fundamental structure, with (I) and (II) isomorphous and with the unit-cell constants of (III) similar to the reduced unit-cell constants of (I) and (II). The distorted square-planar [CuCl $_{3}(H$ $_{2}O)]$ $^{-}$ complex [mirror symmetric in (I) and (II)] forms two semicoordinate Cu Cl bonds to a neighboring complex to produce a dimer with 2/ m symmetry [only inversion symmetry in (III)]. The semicoordinate Cu Cl bond length of the dimer shows significant elongation at 295 K compared with that at 100 K, while the coordinate Cu-Cl bond lengths are slightly contracted at 295 K compared with those at 100 K. The inorganic dimers are linked by eight hydrogen bonds to four neighboring dimers to establish a checkerboard network layer in the ab plane, with voids between the dimers that accommodate, on both sides, inversion-related organic cation pairs. The organic cations are required by mirror-plane symmetry to be disordered in (I) and (II). The organic cations and [CuCl $_{3}(H$ $_{2}O)]$ $^{-}$ complexes are nearly coplanar and tilted out of the layer plane to establish a hybrid organic-inorganic layer structure parallel to (202) [(11 ) in (III)], with hydrate columns (defined by water molecules) and hydrophobic columns (defined by methyl groups) parallel to each other [and along the 2 $_{1}$ axes in (I) and (II)]. In 1,1-dimethylpiperidinium aquatrichloridocuprate(II), (C $_{7}H$ $_{16}N)[CuCl$ $_{3}(H$ $_{2}O)],$ (IV), the bulkier organic cation prevents semicoordinate bonding between complexes, which are hydrogen bonded side-to-side in zigzag chains that place water molecules in columns along half of the 2 $_{1}$ axes.
File Format	HTM / HTML
e-ISSN	20532296
Journal	Acta Crystallographica Section C Crystal Structure Communications
Issue Number	Pt 6
Volume Number	67
Language	English
Publisher	IUCr/Wiley
Publisher Date	2011-06-01
Publisher Place	United States
Access Restriction	Open
Subject Keyword	Discipline Analytical Chemistry Discipline Crystallography
Content Type	Text
Resource Type	Article

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