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| Content Provider | World Health Organization (WHO)-Global Index Medicus |
|---|---|
| Author | Kohri, Michinari Shinoda, Yoshihiro Kohma, Hiroto Nannichi, Yuri Yamauchi, Mitsuaki Yagai, Shiki Kojima, Takashi Taniguchi, Tatsuo Kishikawa, Keiki |
| Description | Country affiliation: Japan Author Affiliation: Kohri M ( Division of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba, 263-8522, Japan. kohri@faculty.chiba-u.jp) |
| Abstract | A free-standing polymer brush film with tailored thicknesses based on a colorless polydopamine (PDA) thin layer is prepared and characterized. The surface-initiated atom transfer radical polymerization (ATRP) of 2-hydroxyethyl methacrylate (HEMA) is performed on a PDA layer with thickness of ca. 6 nm, which generated an optically transparent and colorless free-standing PHEMA brush film (1.5 cm × 1.5 cm). Because the cross-linked PDA layer is used as the base for the polymer brushes, the reported method does not require cross-linking the polymer brushes. The free-standing film thicknesses of ≈16-75 nm are controlled by simply changing the ATRP reaction time. The results show that the free-standing PHEMA brush film transferred onto a plate exhibits a relatively smooth surface and is stable in any solvent. |
| File Format | HTM / HTML |
| ISSN | 10221336 |
| Issue Number | 15 |
| Journal | Macromolecular Rapid Communications |
| Volume Number | 34 |
| e-ISSN | 15213927 |
| Language | English |
| Publisher | Wiley |
| Publisher Date | 2013-08-01 |
| Publisher Place | Germany |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Discipline Molecula Biology Discipline Biochemistry Indoles Chemical Synthesis Membranes, Artificial Methacrylates Polymers Chemistry Journal Article Research Support, Non-u.s. Gov't |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry Materials Chemistry Polymers and Plastics |
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