NDLI: Stable carbon and nitrogen isotope ratios of sodium and potassium cyanide as a forensic signature.

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Stable carbon and nitrogen isotope ratios of sodium and potassium cyanide as a forensic signature.

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Kreuzer, Helen W. Horita, Juske Moran, James J. Tomkins, Bruce A. Janszen, Derek B. Carman, April
Description	Country affiliation: United States Author Affiliation: Kreuzer HW ( Chemical and Biological Signature Sciences, Pacific Northwest National Laboratory, Richland, WA 99352, USA. Helen.Kreuzer@pnl.gov)
Abstract	Sodium and potassium cyanide are highly toxic, produced in large amounts by the chemical industry, and linked to numerous high-profile crimes. The U.S. Centers for Disease Control and Prevention has identified cyanide as one of the most probable agents to be used in a chemical terrorism event. We investigated whether stable C and N isotopic content of sodium and potassium cyanide could serve as a forensic signature for sample matching, using a collection of 65 cyanide samples. Upon analysis, a few of the cyanide samples displayed nonhomogeneous isotopic content associated with degradation to a carbonate salt and loss of hydrogen cyanide. Most samples had highly reproducible isotope content. Of the 65 cyanide samples, >95% could be properly matched based on C and N isotope ratios, with a false match rate <3%. These results suggest that stable C and N isotope ratios are a useful forensic signature for matching cyanide samples.
File Format	HTM / HTML
ISSN	00221198
Issue Number	1
Journal	Journal of Forensic Sciences
Volume Number	57
e-ISSN	15564029
Language	English
Publisher	Wiley-Blackwell
Publisher Date	2012-01-01
Publisher Place	United States
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Discipline Forensic Sciences
Content Type	Text
Resource Type	Article
Subject	Genetics Pathology and Forensic Medicine

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