NDLI: Glycan arrays on aluminum-coated glass slides.

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Chemoselective oxidation of alcohols by a H2O2-Pt black system under organic solvent- and halide-free conditions.

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Combinatorial design of simplified high-performance chiral phase-transfer catalysts for practical asymmetric synthesis of alpha-alkyl- and alpha,alpha-dialkyl-alpha-amino acids.

Glycan arrays on aluminum-coated glass slides.

Tandem hydroformylation-hydrogenation of 1-decene catalyzed by Rh-bidentate bis(trialkylphosphine)s.

Enantioselective synthesis of the fully functionalized ABC ring of zoanthenol.

Congratulations to Professor Ryoji Noyori on his 70th birthday.

'What next?' Congratulations!

Year: 2007 Volume: 2

Year: 2006 Volume: 1

Glycan arrays on aluminum-coated glass slides.

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Tseng, Susan Y. Wang, Cheng-Chi Lin, Chin-Wei Chen, Cheng-Lung Yu, Wen-Yueh Chen, Chung-Hsuan Wu, Chung-Yi Wong, Chi-Huey
Description	Country affiliation: Taiwan Author Affiliation: Tseng SY ( Genomics Research Center, Academia Sinica, Taiwan.)
Abstract	We have developed a novel method of immobilizing glycans onto aluminum-coated glass (ACG) slides for potential use in disease diagnosis and drug discovery. The quality of these sugar chips can be assessed by mass spectrometry and fluorescence measurements with high sensitivity. The unique properties of ACG slides include: 1) the metal oxide layer on the surface can be activated for grafting organic compounds such as modified oligosaccharides; 2) the surface remains electrically conductive, and the grafted oligosaccharides can be simultaneously characterized by mass spectrometry and carbohydrate-binding assay; and 3) the slides are more sensitive than transparent glass slides in binding analysis. To demonstrate this, we synthesized a model compound of mannose with a built-in photocleavable linker bound to the ACG slide surface. The molecular weight of the grafted mannose was identified by mass spectrometry, and the slide was subjected to biotinylated ConA binding followed by Cy3-tagged streptavidin detection. This method was further extended to the preparation of glycan arrays containing lactose and the cancer antigen Globo H.
File Format	HTM / HTML
ISSN	18614728
Issue Number	8-9
Volume Number	3
e-ISSN	1861471X
Journal	Chemistry - An Asian Journal
Language	English
Publisher	Wiley-VCH
Publisher Date	2008-09-01
Publisher Place	Germany
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Microscopy, Electron, Scanning Aluminum Cross-linking Reagents Glass Mannose Journal Article Proteins Chemistry Polysaccharides Analysis Mass Spectrometry Surface Properties Discipline Chemistry Molecular Structure Spectrum Analysis Photochemistry
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Biochemistry

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