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Electric double-layer capacitor based on an ionic clathrate hydrate.

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Year: 2013 Volume: 8 Issue: 6

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Electric double-layer capacitor based on an ionic clathrate hydrate.

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Lee, Wonhee Kwon, Minchul Park, Seongmin Lim, Dongwook Cha, Jong-Ho Lee, Huen
Description	Author Affiliation: Lee W ( Department of Chemical and Biomolecular Engineering (BK21 program) and Graduate school of EEWS, Korea Advanced Institute of Science and Technology, Daejeon 305-701, Rep. of Korea.)
Abstract	Herein, we suggest a new approach to an electric double-layer capacitor (EDLC) that is based on a proton-conducting ionic clathrate hydrate (ICH). The ice-like structures of clathrate hydrates, which are comprised of host water molecules and guest ions, make them suitable for applications in EDLC electrolytes, owing to their high proton conductivities and thermal stabilities. The carbon materials in the ICH Me4NOHâ5 H2O show a high specific capacitance, reversible charge-discharge behavior, and a long cycle life. The ionic-hydrate complex provides the following advantages in comparison with conventional aqueous and polymer electrolytes: 1)âThe ICH does not cause leakage problems under normal EDLC operating conditions. 2)âThe hydrate material can be utilized itself, without requiring any pre-treatments or activation for proton conduction, thus shortening the preparation procedure of the EDLC. 3)âThe crystallization of the ICH makes it possible to tailor practical EDLC dimensions because of its fluidity as a liquid hydrate. 4)âThe hydrate solid electrolyte exhibits more-favorable electrochemical stability than aqueous and polymer electrolytes. Therefore, ICH materials are expected to find practical applications in versatile energy devices that incorporate electrochemical systems.
File Format	HTM / HTML
ISSN	18614728
Issue Number	7
Journal	Chemistry - An Asian Journal
Volume Number	8
e-ISSN	1861471X
Language	English
Publisher	Wiley-VCH
Publisher Date	2013-07-01
Publisher Place	Germany
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Discipline Chemistry
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Biochemistry

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