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Chiral Sensing of Various Amino Acids Using Induced Circularly Polarized Luminescence from Europium(III) Complexes of Phenanthroline Dicarboxylic Acid Derivatives.

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Chiral Sensing of Various Amino Acids Using Induced Circularly Polarized Luminescence from Europium(III) Complexes of Phenanthroline Dicarboxylic Acid Derivatives.

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Uchida, Taka-Aki Nozaki, Koichi Iwamura, Munetaka
Description	Country affiliation: Japan Author Affiliation: Uchida TA ( Graduated School of Science and Engineering, University of Toyama, Gofuku, 3190, Toyama, Japan.); Nozaki K ( Graduated School of Science and Engineering, University of Toyama, Gofuku, 3190, Toyama, Japan.); Iwamura M ( Graduated School of Science and Engineering, University of Toyama, Gofuku, 3190, Toyama, Japan. miwamura@sci.u-toyama.ac.jp.)
Abstract	Circularly polarized luminescence (CPL) was observed from [Eu(dppda)2 ](-) (dppda=4,7-diphenyl-1,10-phenanthroline-2,9-dicarboxylic acid) and [Eu(pzpda)2 ](-) (pzpda=pyrazino[2,3-f][1,10]phenanthroline-7,10-dicarboxylic acid) in aqueous solutions containing various amino acids. The selectivity of these complexes towards amino acids enabled them to be used as chiral sensors and their behavior was compared with that of [Eu(pda)2 ](-) (pda=1,10-phenanthroline-2,9-dicarboxylic acid). As these Eu(III) complexes have achiral D2d structures under ordinary conditions, there were no CPL signals in the emission assigned to f-f transitions. However, when the solutions contained particular amino acids they exhibited detectable CPL signals with glum values of about 0.1 (glum =CPL/2 TL; TL=total luminescence). On examining 13 amino acids with these three Eu(III) complexes, it was found that whether an amino acid induced a detectable CPL depended on the Eu(III) complex ligands. For example, when ornithine was used as a chiral agent, only [Eu(dppda)2 ](-) exhibited intense CPL in aqueous solutions of 10(-2) âmol dm(-3) . Steep amino acid concentration dependence suggested that CPL in [Eu(dppda)2 ](-) and [Eu(pzpda)2 ](-) was induced by the association of four or more amino acid molecules, whereas CPL in [Eu(pda)2 ](-) was induced by association of two arginine molecules.
File Format	HTM / HTML
ISSN	18614728
Issue Number	17
Journal	Chemistry - An Asian Journal
Volume Number	11
e-ISSN	1861471X
Language	English
Publisher	Wiley-VCH
Publisher Date	2016-09-06
Publisher Place	Germany
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Discipline Chemistry
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Biochemistry

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