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| Content Provider | World Health Organization (WHO)-Global Index Medicus |
|---|---|
| Author | Zhang, Zehui Dong, Kun Zhao, Zongbao Kent |
| Description | Author Affiliation: Zhang Z ( Dalian Institute of Chemical Physics, CAS, PR China. zhangzehui@dicp.ac.cn) |
| Abstract | A clean, facile, and environment-friendly catalytic method has been developed for the conversion of furfuryl alcohol into alkyl levulinates making use of the novel solid catalyst methylimidazolebutylsulfate phosphotungstate ([MIMBS]3PW12O40). The solid catalyst is an organic-inorganic hybrid material, which consists of an organic cation and an inorganic anion. A study for optimizing the reaction conditions such as the reaction time, the temperature and the catalyst loading has been performed. Under optimal conditions, a high n-butyl levulinate yield of up to 93 % is obtained. Furthermore, the kinetics of the reaction pathways and the mechanism for the alcoholysis of furfuryl alcohol are discussed. This method is environmentally benign and economical for the conversion of biomass-based derivatives into fine chemicals. |
| File Format | HTM / HTML |
| ISSN | 18645631 |
| Issue Number | 1 |
| Volume Number | 4 |
| e-ISSN | 1864564X |
| Journal | ChemSusChem |
| Language | English |
| Publisher | Wiley-VCH |
| Publisher Date | 2011-01-17 |
| Publisher Place | Germany |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Water Green Chemistry Technology Research Support, Non-u.s. Gov't Temperature Discipline Sustainable Chemistry Butanols Journal Article Chemistry Acids Levulinic Acids Furans Catalysis Kinetics Methods |
| Content Type | Text |
| Resource Type | Article |
| Subject | Energy Environmental Chemistry Materials Science Chemical Engineering |
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