NDLI: Competing Reactions of $CO_{2}$ with Cations and Anions in Azolide Ionic Liquids

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Competing Reactions of $CO_{2}$ with Cations and Anions in Azolide Ionic Liquids

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Gohndrone, Thomas R. Bum Lee, Tae DeSilva, M. Aruni Quiroz-Guzman, Mauricio Schneider, William F. Brennecke, Joan F.
Description	Author Affiliation: Gohndrone TR ( Department of Chemical and Biomolecular Engineering, University of Notre Dame, Notre Dame, Indiana 46556 (United States).)
Abstract	We show that phosphonium azolide ionic liquids of interest for $CO_{2}$ capture applications react with $CO_{2}$ both through the normal anion channel and, at elevated temperatures, through a previously unrecognized cation channel. The reaction is caused by an interaction between the anion and cation that allows proton transfer, and involves a phosphonium ylide intermediate. The cation reaction can be mitigated by using ammonium rather than phosphonium cations. Thus, phosphonium and ammonium cations paired with aprotic heterocyclic anions (AHAs) react with $CO_{2}$ through different mechanisms at elevated temperatures. This work shows that careful consideration of both physical properties and chemical reactivity of ILs based on AHA anions is needed when designing ionic liquids for $CO_{2}$ separations.
File Format	HTM / HTML
ISSN	18645631
Issue Number	7
Volume Number	7
e-ISSN	1864564X
Journal	ChemSusChem
Language	English
Publisher	Wiley-VCH
Publisher Date	2014-07-01
Publisher Place	Germany
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Ionic Liquids Research Support, N.i.h., Extramural Research Support, U.s. Gov't, Non-p.h.s. Research Support, Non-u.s. Gov't Ammonium Compounds Molecular Conformation Discipline Sustainable Chemistry Isolation & Purification Organophosphorus Compounds Models, Molecular Carbon Dioxide Journal Article Chemistry Adsorption
Content Type	Text
Resource Type	Article
Subject	Energy Environmental Chemistry Materials Science Chemical Engineering

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