NDLI: Metal-free Nanoporous Carbon as a Catalyst for Electrochemical Reduction of $CO_{2}$ to CO and $CH

Please wait, while we are loading the content...

Hybrid Amine-Functionalized Graphene Oxide as a Robust Bifunctional Catalyst for Atmospheric Pressure Fixation of Carbon Dioxide using Cyclic Carbonates

Evaluation of Metal-Organic Frameworks and Porous Polymer Networks for $CO_{2}-Capture$ Applications

The Role of $MgCl_{2}$ as a Lewis Base in $ROMgCl–MgCl_{2}$ Electrolytes for Magnesium-Ion Batteries

Levulinic Acid Biorefineries: New Challenges for Efficient Utilization of Biomass.

In Situ Fluorine Doping of $TiO_{2}$ Superstructures for Efficient Visible-Light Driven Hydrogen Generation

Direct Conversion of Greenhouse Gas $CO_{2}$ into Graphene via Molten Salts Electrolysis

Investigation of the Hydrogenation of 5-Methylfurfural by Noble Metal Nanoparticles in a Microcapillary Reactor.

CdS Nanowires Decorated with Ultrathin MoS2 Nanosheets as an Efficient Photocatalyst for Hydrogen Evolution.

Dye-Sensitized $Cu_{2}XSnS_{4}$ (X=Zn, Ni, Fe, Co, and Mn) Nanofibers for Efficient Photocatalytic Hydrogen Evolution

Electrochemical Reduction of Carbon Dioxide to Methanol by Direct Injection of Electrons into Immobilized Enzymes on a Modified Electrode

Catalytic Isomerization of Biomass-Derived Aldoses: A Review.

Corrigendum: Organic Carbonates: Efficient Extraction Solvents for the Synthesis of HMF in Aqueous Media with Cerium Phosphates as Catalysts.

Corrigendum: Levulinic Acid Biorefineries: New Challenges for Efficient Utilization of Biomass.

Year: 2016 Volume: 9 Issue: 5

Year: 2016 Volume: 9 Issue: 4

Year: 2016 Volume: 9 Issue: 3

Year: 2016 Volume: 9 Issue: 2

Year: 2016 Volume: 9 Issue: 1

Metal-free Nanoporous Carbon as a Catalyst for Electrochemical Reduction of $CO_{2}$ to CO and $CH_{4}$

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Li, Wanlu Seredych, Mykola Rodríguez-Castellón, Enrique Bandosz, Teresa J.
Description	Country affiliation: United States Author Affiliation: Li W ( The City College of New York, Department of Chemistry, 160 Convent Avenue, New York, NY, 10031, USA.); Seredych M ( Ph.D. Program in Chemistry, The Graduate Center of the City University of New York, 365 Fifth Avenue, New York, NY, 10016, USA.); Rodríguez-Castellón E ( The City College of New York, Department of Chemistry, 160 Convent Avenue, New York, NY, 10031, USA.); Bandosz TJ ( Departamento de Química Inorgánica, Universidad de Málaga, Málaga, 29071, Spain.)
Abstract	S-doped and dual S,N-doped polymer-derived carbons were studied as electrocatalysts for the reduction of $CO_{2}.$ Higher Faradaic efficiencies for conversion to CO and $CH_{4}$ were obtained for S,N-doped carbon than its S-doped counterpart. The former showed a maximum Faradaic efficiency of 11.3 % for CO and 0.18 % for $CH_{4}$ formation. The S,N-nanoporous carbon was better at decreasing the overpotential of the reduction process. The pyridinic nitrogen groups were found to be actively participating in binding $CO_{2}.$ The quaternary nitrogen and thiophenic groups were also involved in the reduction process. It is proposed that the positively charged sites on the carbon atoms, adjacent to pyridinic nitrogen, stabilize the $CO_{2}^{.−}$ and COOH* intermediates, promoting the formation of CO. The surface basicity of the catalysts improved the $CO_{2}$ reduction selectivity when competing with $H_{2}$ evolution. $N_{2}$ adsorption measurements suggested that ultra-micropores enhance the reduction of $CO_{2}$ to $CH_{4}.$
File Format	HTM / HTML
ISSN	18645631
Issue Number	6
Journal	ChemSusChem
Volume Number	9
e-ISSN	1864564X
Language	English
Publisher	Wiley-VCH
Publisher Date	2016-03-21
Publisher Place	Germany
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Discipline Sustainable Chemistry
Content Type	Text
Resource Type	Article
Subject	Energy Environmental Chemistry Materials Science Chemical Engineering

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Study of Pyridine-Mediated Electrochemical Reduction of $CO_{2}$ to Methanol at High $CO_{2}$ Pressure

Engineering Transition-Metal-Coated Tungsten Carbides for Efficient and Selective Electrochemical Reduction of $CO_{2}$ to Methane

Ni Nanoparticles Supported on Cage-Type Mesoporous Silica for $CO_{2}$ Hydrogenation with High $CH_{4}$ Selectivity

Nitrogen-Doped Carbon Nanotubes as a Highly Active Metal-Free Catalyst for Selective Oxidation

Chemoselective Synthesis of Carbamates using $CO_{2}$ as Carbon Source

Manganese Oxide Nanorod-Decorated Mesoporous ZSM-5 Composite as a Precious-Metal-Free Electrode Catalyst for Oxygen Reduction

Microbes as Electrochemical $CO_{2}$ Conversion Catalysts

Bioinspired Electrocatalytic $CO_{2}$ Reduction by Bovine Serum Albumin-Capped Silver Nanoclusters Mediated by $[α-SiW_{12}O_{40}]^{4−}$

Graphene from Alginate Pyrolysis as a Metal-Free Catalyst for Hydrogenation of Nitro Compounds.

Metal-free Nanoporous Carbon as a Catalyst for Electrochemical Reduction of $CO_{2}$ to CO and $CH_{4}$

Similar Documents

Study of Pyridine-Mediated Electrochemical Reduction of $CO_{2}$ to Methanol at High $CO_{2}$ Pressure

Engineering Transition-Metal-Coated Tungsten Carbides for Efficient and Selective Electrochemical Reduction of $CO_{2}$ to Methane

Ni Nanoparticles Supported on Cage-Type Mesoporous Silica for $CO_{2}$ Hydrogenation with High $CH_{4}$ Selectivity

Nitrogen-Doped Carbon Nanotubes as a Highly Active Metal-Free Catalyst for Selective Oxidation

Chemoselective Synthesis of Carbamates using $CO_{2}$ as Carbon Source

Manganese Oxide Nanorod-Decorated Mesoporous ZSM-5 Composite as a Precious-Metal-Free Electrode Catalyst for Oxygen Reduction

Microbes as Electrochemical $CO_{2}$ Conversion Catalysts

Bioinspired Electrocatalytic $CO_{2}$ Reduction by Bovine Serum Albumin-Capped Silver Nanoclusters Mediated by $[α-SiW_{12}O_{40}]^{4−}$

Graphene from Alginate Pyrolysis as a Metal-Free Catalyst for Hydrogenation of Nitro Compounds.

Metal-free Nanoporous Carbon as a Catalyst for Electrochemical Reduction of $CO_{2}$ to CO and $CH_{4}$