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| Content Provider | World Health Organization (WHO)-Global Index Medicus |
|---|---|
| Author | Siankevich, Sviatlana Fei, Zhaofu Scopelliti, Rosario Jessop, Philip G. Zhang, Jiaguang Yan, Ning Dyson, Paul J. |
| Description | Country affiliation: Switzerland Author Affiliation: Siankevich S ( Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015, Lausanne, Switzerland.); Fei Z ( Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015, Lausanne, Switzerland.); Scopelliti R ( Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015, Lausanne, Switzerland.); Jessop PG ( Department of Chemistry, Queen's University, Kingston, Ontario, K7 L 3N6, Canada.); Zhang J ( Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, 117585, Singapore, Singapore.); Yan N ( Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, 117585, Singapore, Singapore. ning.yan@nus.edu.sg.); Dyson PJ ( Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015, Lausanne, Switzerland. paul.dyson@epfl.ch.) |
| Abstract | Platform chemicals are usually derived from petrochemical feedstocks. A sustainable alternative commences with lignocellulosic biomass, a renewable feedstock, but one that is highly challenging to process. Ionic liquids (ILs) are able to solubilize biomass and, in the presence of catalysts, convert the biomass into useful platform chemicals. Herein, we demonstrate that mixtures of ILs are powerful systems for the selective catalytic transformation of cellulose into 5-hydroxymethylfurfural (HMF). Combining ILs with continuous HMF extraction into methyl-isobutyl ketone or 1,2-dimethoxyethane, which form a biphase with the IL mixture, allows the online separation of HMF in high yield. This one-step process is operated under relatively mild conditions and represents a significant step forward towards sustainable HMF production. |
| File Format | HTM / HTML |
| ISSN | 18645631 |
| Issue Number | 16 |
| Journal | ChemSusChem |
| Volume Number | 9 |
| e-ISSN | 1864564X |
| Language | English |
| Publisher | Wiley-VCH |
| Publisher Date | 2016-08-23 |
| Publisher Place | Germany |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Discipline Sustainable Chemistry |
| Content Type | Text |
| Resource Type | Article |
| Subject | Energy Environmental Chemistry Materials Science Chemical Engineering |
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