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| Content Provider | World Health Organization (WHO)-Global Index Medicus |
|---|---|
| Author | Biasin, Elisa Van Driel, Tim Brandt Kjær, Kasper S. Dohn, Asmus O. Christensen, Morten Harlang, Tobias Chabera, Pavel Liu, Yizhu Uhlig, Jens Pápai, Mátyás Németh, Zoltán Hartsock, Robert Liang, Winnie Zhang, Jianxin Alonso-Mori, Roberto Chollet, Matthieu Glownia, James M. Nelson, Silke Sokaras, Dimosthenis Assefa, Tadesse A. Britz, Alexander Galler, Andreas Gawelda, Wojciech Bressler, Christian Gaffney, Kelly J. Lemke, Henrik T. Møller, Klaus B. Nielsen, Martin M. Sundström, Villy Vankó, György Wärnmark, Kenneth Canton, Sophie E. Haldrup, Kristoffer |
| Description | Country affiliation: Denmark Author Affiliation: Biasin E ( Department of Physics, Technical University of Denmark, Fysikvej 307, DK-2800 Kongens Lyngby, Denmark.); van Driel TB ( Department of Physics, Technical University of Denmark, Fysikvej 307, DK-2800 Kongens Lyngby, Denmark.); Kjær KS ( Department of Physics, Technical University of Denmark, Fysikvej 307, DK-2800 Kongens Lyngby, Denmark.); Dohn AO ( Department of Chemical Physics, Lund University, Box 118, S-22100 Lund, Sweden.); Christensen M ( PULSE Institute, SLAC National Accelerator Laboratory, Menlo Park, California 94025, USA.); Harlang T ( Department of Chemistry, Technical University of Denmark, Kemitorvet 207, DK-2800 Kongens Lyngby, Denmark.); Chabera P ( Department of Physics, Technical University of Denmark, Fysikvej 307, DK-2800 Kongens Lyngby, Denmark.); Liu Y ( Department of Chemical Physics, Lund University, Box 118, S-22100 Lund, Sweden.); Uhlig J ( Department of Chemical Physics, Lund University, Box 118, S-22100 Lund, Sweden.); Pápai M ( Department of Chemical Physics, Lund University, Box 118, S-22100 Lund, Sweden.); Németh Z ( Centre for Analysis and Synthesis, Department of Chemistry, Lund University, Box 124, Lund SE-22100, Sweden.); Hartsock R ( Department of Chemical Physics, Lund University, Box 118, S-22100 Lund, Sweden.); Liang W ( Department of Chemistry, Technical University of Denmark, Kemitorvet 207, DK-2800 Kongens Lyngby, Denmark.); Zhang J ( Wigner Research Centre for Physics, Hungarian Academy Sciences, H-1525 Budapest, Hungary.); Alonso-Mori R ( Wigner Research Centre for Physics, Hungarian Academy Sciences, H-1525 Budapest, Hungary.); Chollet M ( PULSE Institute, SLAC National Accelerator Laboratory, Menlo Park, California 94025, USA.); Glownia JM ( PULSE Institute, SLAC National Accelerator Laboratory, Menlo Park, California 94025, USA.); Nelson S ( School of Environmental and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387, China.); Sokaras D ( LCLS, SLAC National Accelerator Laboratory, Menlo Park, California 94025, USA.); Assefa TA ( LCLS, SLAC National Accelerator Laboratory, Menlo Park, California 94025, USA.); Britz A ( LCLS, SLAC National Accelerator Laboratory, Menlo Park, California 94025, USA.); Galler A ( LCLS, SLAC National Accelerator Laboratory, Menlo Park, California 94025, USA.); Gawelda W ( LCLS, SLAC National Accelerator Laboratory, Menlo Park, California 94025, USA.); Bressler C ( European XFEL GmbH, Albert-Einstein-Ring 19, D-22761 Hamburg, Germany.); Gaffney KJ ( European XFEL GmbH, Albert-Einstein-Ring 19, D-22761 Hamburg, Germany.); Lemke HT ( European XFEL GmbH, Albert-Einstein-Ring 19, D-22761 Hamburg, Germany.); Møller KB ( European XFEL GmbH, Albert-Einstein-Ring 19, D-22761 Hamburg, Germany.); Nielsen MM ( Institute of Physics, Jan Kochanowski University, 25-406 Kielce, Poland.); Sundström V ( European XFEL GmbH, Albert-Einstein-Ring 19, D-22761 Hamburg, Germany.); Vankó G ( PULSE Institute, SLAC National Accelerator Laboratory, Menlo Park, California 94025, USA.); Wärnmark K ( LCLS, SLAC National Accelerator Laboratory, Menlo Park, California 94025, USA.); Canton SE ( SwissFEL, Paul Scherrer Institut, 5232 Villigen PSI, Switzerland.); Haldrup K ( Department of Chemistry, Technical University of Denmark, Kemitorvet 207, DK-2800 Kongens Lyngby, Denmark.) |
| Abstract | We study the structural dynamics of photoexcited $ [ Co ( terpy ) _{ 2 } ] ^{ 2 + } $ in an aqueous solution with ultrafast x-ray diffuse scattering experiments conducted at the Linac Coherent Light Source. Through direct comparisons with density functional theory calculations, our analysis shows that the photoexcitation event leads to elongation of the Co-N bonds, followed by coherent Co-N bond length oscillations arising from the impulsive excitation of a vibrational mode dominated by the symmetrical stretch of all six Co-N bonds. This mode has a period of 0.33 ps and decays on a subpicosecond time scale. We find that the equilibrium bond-elongated structure of the high spin state is established on a single-picosecond time scale and that this state has a lifetime of $ ∼ 7 ps $ . |
| File Format | HTM / HTML |
| ISSN | 00319007 |
| e-ISSN | 10797114 |
| Journal | Physical Review Letters |
| Issue Number | 1 |
| Volume Number | 117 |
| Language | English |
| Publisher | American Physical Society |
| Publisher Date | 2016-07-01 |
| Publisher Place | United States |
| Access Restriction | Open |
| Subject Keyword | Physics |
| Content Type | Text |
| Resource Type | Article |
| Subject | Physics and Astronomy |
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