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| Content Provider | World Health Organization (WHO)-Global Index Medicus |
|---|---|
| Author | Freire, Layla F. A. da Fonseca, Fabiana Valéria Yokoyama, Lidia Teixeira, Luiz Alberto Cesar |
| Description | Author Affiliation: Freire LF ( School of Chemistry, Universidade Federal do Rio de Janeiro, 21941-909, Rio de Janeiro - RJ, Brazil E-mail: fabiana@eq.ufrj.br.); da Fonseca FV ( School of Chemistry, Universidade Federal do Rio de Janeiro, 21941-909, Rio de Janeiro - RJ, Brazil E-mail: fabiana@eq.ufrj.br.); Yokoyama L ( School of Chemistry, Universidade Federal do Rio de Janeiro, 21941-909, Rio de Janeiro - RJ, Brazil E-mail: fabiana@eq.ufrj.br.); Teixeira LA ( Pontifícia Universidade Católica do Rio de Janeiro and Peróxidos do Brasil Ltda. (Solvay Group), 22451-041, Rio de Janeiro - RJ, Brazil.) |
| Abstract | This study evaluated the use of a Fenton's reaction in a falling film solar reactor (FFR), as a possible advanced oxidation process for the mineralization of the organic compound phenol in water. Preliminary tests were carried out to evaluate phenol degradation by photolysis and to select the optimal residence time in which to carry out the process using a solar photo-Fenton system. The variables studied were the initial phenol concentration (100 to 300 mg L(-1)), the [Phenol]:[H2O2] mass ratio (1.0 to 2.0) and the [H2O2]/[Fe2+] molar ratio (5 to 10). Phenol degradation of 99% and chemical oxygen demand (COD) reduction of 97% were obtained under the following reaction conditions: phenol concentration=200 mg L(-1), mass ratio [Phenol]:[H2O2]=1.5 and molar ratio [H2O2]/[Fe2+]=7.5. Overall mineralization was achieved using the solar photo-Fenton process to destroy phenol and COD. The solar photo-Fenton process using a FFR appears to be a viable method for removing phenols in wastewaters on an industrial scale. |
| File Format | HTM / HTML |
| ISSN | 02731223 |
| Issue Number | 5 |
| Volume Number | 70 |
| e-ISSN | 19969732 |
| Journal | Water Science & Technology |
| Language | English |
| Publisher | IWA Publishing |
| Publisher Date | 2014-01-01 |
| Publisher Place | Great Britain (UK) |
| Access Restriction | Subscribed |
| Subject Keyword | Discipline Hydrology Hydrogen Peroxide Chemistry Iron Phenol Photolysis Waste Disposal, Fluid Methods Water Pollutants, Chemical Biological Oxygen Demand Analysis Hydrogen-ion Concentration Oxidation-reduction Phenols Sunlight Waste Water Water Journal Article Research Support, Non-u.s. Gov't |
| Content Type | Text |
| Resource Type | Article |
| Subject | Environmental Engineering Water Science and Technology |
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