NDLI: Synthetic control method for crystallite size of MOF-5

Please wait, while we are loading the content...

Synthesis of a new two-dimensional Cd(II) coordination compound by benzotriazole-5-carboxylate acid and 1,10-phenanthroline and its crystal structure and characterization

Ternary solid nano organic/inorganic composite of lanthanum with acetic acid and curcumin/hydroxyapatite and its antibacterial activity

Synthetic control method for crystallite size of MOF-5

Coumarin modified rhodamine derivative: Fluorescent chemosensor selectively recognizing Al$^{3+}$ and Ca$^{2+}$

Dispersive liquid-liquid microextraction for simultaneous determination of six parabens in aqueous cosmetics

Synthesis, characterization and application of organic-inorganic hybrid and carbaryl-imprinted capillary monolithic column

Water-soluble porphyrin as temperature sensor based on fluorescent enhancement

Synthesis and characterization of novel Schiff base macrocyclic compounds containing thiophene

One-pot synthesis of 1,5-diaza-2,6-cyclooctadiene-3,7-dicarboxylates through a multiple-component reaction

Synthesis and biological activities of novel 1,2,4-triazole derivatives containing 1,2,3-thiadiazole ring

Enzymatic promiscuity: “Amano” lipase AS-catalysed synthesis of naphthopyran derivatives in anhydrous media

Synthesis and herbicidal activities of novel uracil derivatives containing pyrimidinyl moiety

Mild and efficient synthesis of 1-(6-chloroquinoxalin-2-yl)-2-[4-(trifluoromethyl)-2,6-dinitrophenyl] hydrazine derivatives by microwave irradiation

Syntheses and biological activities of novel 3-bromo-1-(3-chloropyridin-2-yl)-N-hydroxy-N-aryl-1H-pyrazole-5-carboxamides

Synthesis and crystal structure of p-tert-butylcalix[4]arene 1,3-distal and monosubstituted semicarbazones and thiosemicarbazones

Synthesis and antitumor activity of a new 7-azaindole derivative

Syntheses, electrochemical behaviors, spectral properties and DFT calculations of two 1,3-dithiole derivatives

Preparation and characterization of SiO$_{2}$-coated 2,4-hexadiyn-1,6-bis(ethylurea) microcapsules

Electrochemical method to characterize multidrug resistance

KOH direct activation for preparing activated carbon fiber from polyacrylonitrile-based pre-oxidized fiber

Rapid evaluation of individual hydrogen bonding energies in linear water chains

Theoretical calculations of the pK $_{a}$ values of 1-aryl-4-propylpiperazine drugs in aqueous solution

DNA binding properties and cytotoxic activities of two trinuclear ruthenium(II) polypyridyl complexes

Synthesis and thermal behavior of 1,8-dihydroxy-4,5-dinitroanthraquinone manganese salt

Highly efficient co-removal of heavy metals in wastewater from chemical oxygen demand testing instrument by cysteine-functionalized magnetic nanoparticles

Mechanism construction and simulation for high-temperature combustion of n-propylcyclohexane

Electrochemistry of CeCl$_{3}$ in molten LiCl-KCl eutectic

Interactions of phenanthroline compounds with i-motif DNA

Corrosion of nickel-based alloy G30 in the stratum water containing H$_{2}$S/CO$_{2}$

Effect of doped boron on the properties of ZnO thin films prepared by sol-gel spin coating

Theoretical and experimental studies on photophysical characteristics of low bandgap polymers

Underwater oil wettability on nanostructured superamphiphobic surface tuned by trapped air layer continuity

Pine needle-like nanocomposite: Supercritical CO$_{2}$ assisted polythiophene synthesis on carbon nanotubes

Optimization of preparation process for allylamine-bacterial cellulose via graft copolymerization by response surface methodology

Chemical Research in Chinese Universities : Volume 30, Issue 2, April 2014

Chemical Research in Chinese Universities : Volume 30, Issue 1, February 2014

Chemical Research in Chinese Universities : Volume 29

Synthetic control method for crystallite size of MOF-5

Content Provider	Springer Nature Link
Author	Xu, Junyi Yuan, Changfu Liu, Jin Han, Pengfei
Copyright Year	2014
Abstract	We reported a dripping solvothermal method for synthesizing metal-organic framework-5(MOF-5). It started from separately dissolving Zn(NO$_{3}$)$_{2}$ and terephthalic acid(H$_{2}$BDC) in dimethyl formamide(DMF), and then dripping one solution into the other. Results of SEM, XRD and laser particle size distribution show that regular cubic-shaped and micro-crystallite powder of MOF-5 can be obtained. The d $_{0.5}$(volume-median-diameter) values are 4.32 μm for particles prepared by dripping Zn(NO$_{3}$)$_{2}$ into H$_{2}$BDC(ZH) and 9.32 μm for those prepared by dripping H$_{2}$BDC into Zn(NO$_{3}$)$_{2}$(HZ), much smaller than 22.7 μm that of particles prepared by the traditional adding water solvothermal method(L). The standard deviations of the particle size distributions fitted by the GaussAmp model are 2.49, 4.38 and 15.4 respectively for ZH, HZ and L, further revealing narrower size distributions of particles prepared by the dripping method. In addition, the Langmuir specific surface areas are 923 m$^{2}$/g for ZH and 868 m$^{2}$/g for HZ. The TGA results present mass losses of 4.18% and 3.62% at 105 °C, 17.19% and 14.78% at 245 °C, 39.04% and 34.85% at 600 °C separately for ZH and HZ, which correspond to the removal of H$_{2}$O, DMF and the decomposition of MOF-5. This indicates that MOF-5 has a strong adsorption ability for small molecules. Besides, the mass loss of 48.39%(ZH) and 41.02%(HZ) between 400 °C and 600 °C are less than the theoretical value of 57.81% for MOF-5 decomposition to ZnO, suggesting that an impure phase with an extra amount of ZnO may exist in the cavities of MOF-5.
Starting Page	356
Ending Page	361
Page Count	6
File Format	PDF
ISSN	10059040
Journal	Chemical Research in Chinese Universities
Volume Number	30
Issue Number	3
e-ISSN	22103171
Language	English
Publisher	Jilin University and The Editorial Department of Chemical Research in Chinese Universities
Publisher Date	2014-05-15
Publisher Place	Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Size distribution Chemistry/Food Science Analytical Chemistry Physical Chemistry Dripping solvothermal method Inorganic Chemistry Metal-organic framework-5(MOF-5) Organic Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Education

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Comparison of MOF-5- and Cr-MOF-derived carbons for hydrogen storage application

New method for catalyst preparation based on metal-organic framework MOF-5 for the partial hydrogenation of phenylacetylene

A novel metal-organic framework using heterometallic tetranuclear cluster as secondary building block and isophthalic acid as ligand

Solvothermal synthesis, thermal and adsorption properties of metal-organic frameworks Zn and CoZn(DPB)

Electrochemical performance of metal-organic framework synthesized by a solvothermal method for supercapacitors

Solvothermal synthesis, structural characterization and properties of two new layered lanthanide sulfates

A novel 3D metal organic framework based on an Azolate ligand

Solvothermal synthesis, crystal structure and photoluminescent property of a novel 3D [Ca$_{2}$(HCOO)$_{2}$(nds)(H$_{2}$O)$_{2}$]$_{ n }$

Mixed cobalt/nickel metal–organic framework, an efficient catalyst for one-pot synthesis of substituted imidazoles

Synthetic control method for crystallite size of MOF-5

Similar Documents

Comparison of MOF-5- and Cr-MOF-derived carbons for hydrogen storage application

New method for catalyst preparation based on metal-organic framework MOF-5 for the partial hydrogenation of phenylacetylene

A novel metal-organic framework using heterometallic tetranuclear cluster as secondary building block and isophthalic acid as ligand

Solvothermal synthesis, thermal and adsorption properties of metal-organic frameworks Zn and CoZn(DPB)

Electrochemical performance of metal-organic framework synthesized by a solvothermal method for supercapacitors

Solvothermal synthesis, structural characterization and properties of two new layered lanthanide sulfates

A novel 3D metal organic framework based on an Azolate ligand

Solvothermal synthesis, crystal structure and photoluminescent property of a novel 3D [Ca$_{2}$(HCOO)$_{2}$(nds)(H$_{2}$O)$_{2}$]$_{ n }$

Mixed cobalt/nickel metal–organic framework, an efficient catalyst for one-pot synthesis of substituted imidazoles

Synthetic control method for crystallite size of MOF-5