NDLI: Adsorption separation of CO$_{2}$ and N$_{2}$ on MIL-101 metal-organic framework and activated carbon

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Adsorption separation of CO$_{2}$ and N$_{2}$ on MIL-101 metal-organic framework and activated carbon

Content Provider	Springer Nature Link
Author	Feng, Weisheng Chen, Jihong Li, Pengwei Wang, Xianling
Copyright Year	2013
Abstract	In this work, the CO$_{2}$ and N$_{2}$ adsorption properties of MIL-101 metal-organic framework (MOF) and activated carbon (AC) were investigated using a standard gravimetric method within the pressure range of 0–30 bar and at four different temperatures (298, 308, 318 and 328 K). The dual-site Langmuir–Freundlich (DSLF) model was used to describe the CO$_{2}$ adsorption behaviors on these two adsorbents. The diffusion coefficients and activation energy E $_{a}$ for diffusion of CO$_{2}$ in the MIL-101 and AC samples were estimated separately. Results showed that the isosteric heat of CO$_{2}$ adsorption on the MIL-101 at zero loading was much higher than that on the AC due to a much stronger interaction between CO$_{2}$ molecule and the unsaturated metal sites Cr$^{3+}$ on MIL-101. Meanwhile, the dramatically decreased isosteric heats of CO$_{2}$ adsorption on MIL-101 indicated a more heterogeneous surface of MIL-101. Furthermore, the adsorption kinetic behaviors of CO$_{2}$ on the two samples can be well described by the micropore diffusion model. With the increase of temperature, the diffusion coefficients of CO$_{2}$ in the two samples both increased. The activation energy E $_{a}$ for diffusion of CO$_{2}$ in MIL-101 was slightly lower than that in AC, suggesting that MIL-101 was much favorable for the CO$_{2}$ adsorption. The CO$_{2}$/N$_{2}$ selectivities on MIL-101 and AC were separately estimated to be 13.7 and 9.2 using Henry law constant, which were much higher than those on other MOFs.
Starting Page	741
Ending Page	749
Page Count	9
File Format	PDF
ISSN	1735207X
Journal	Journal of the Iranian Chemical Society
Volume Number	11
Issue Number	3
e-ISSN	17352428
Language	English
Publisher	Springer Berlin Heidelberg
Publisher Date	2013-10-19
Publisher Place	Berlin, Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	MIL-101 Analytical Chemistry Physical Chemistry Carbon dioxide Adsorption isotherms Adsorption kinetics Biochemistry Activated carbon (AC) Inorganic Chemistry Activation energy Organic Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry

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