NDLI: Effect of temperature on tacticity in thermal polymerization of p-methylstyrene by $^{13}$C NMR spectroscopy

Content Provider	Springer Nature Link
Author	Ziaee, Farshid Khoshkhoo, Mahdi Samadi
Copyright Year	2011
Abstract	Poly(p-methylstyrene) (Pp-MS) was synthesized at three different temperatures of 50, 150 and 250 °C via bulk thermal polymerization method. The assignment of all stereosequences at triad and pentad levels for two quaternary aromatic carbons and hexad level for methylene carbon was carried out by $^{13}$C liquid nuclear magnetic resonance spectroscopy (NMR) in deuterated chloroform at similar conditions. The probability of meso addition (P $_{m}$) was calculated from second quaternary aromatic carbon and used to predict the relative intensities of methylene and first quaternary aromatic carbon by Bernoullian and first-order Markov statistical models. The results were compared with experimental data. It is shown that the Bernoullian statistics fit better than first-order Markov model for all three samples. The results indicate that P $_{m}$ increases by increasing polymerization temperature. The corresponding P $_{m}$ values determined for synthesized Pp-MSs at 50, 150 and 250 °C were 0.383, 0.392 and 0.404, respectively. It was observed that higher resolutions and better splitting patterns were achievable by increasing the NMR acquisition temperature from 20 to 50 °C. When temperature increased during NMR acquisition, the resolution improved for the first and second quaternary aromatic carbons and methylene carbon, though there was no splitting pattern observed for methyl carbon atom at the para-position of the aromatic ring.
Starting Page	21
Ending Page	29
Page Count	9
File Format	PDF
ISSN	10261265
Journal	Iranian Polymer Journal
Volume Number	21
Issue Number	1
e-ISSN	17355265
Language	English
Publisher	Springer-Verlag
Publisher Date	2011-12-21
Publisher Place	Berlin, Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Polymer Sciences Tacticity NMR Thermal polymerization Ceramics, Glass, Composites, Natural Methods Microstructure Poly(p-methylstyrene)
Content Type	Text
Resource Type	Article
Subject	Materials Chemistry Chemical Engineering Polymers and Plastics

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