NDLI: Effect of co-initiator on the size distribution of the stable poly(styrene-co-divinylbenzene) microspheres in acetone/water mixture

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Effect of co-initiator on the size distribution of the stable poly(styrene-co-divinylbenzene) microspheres in acetone/water mixture

Content Provider	Springer Nature Link
Author	Choi, Jin Young Lee, Kangseok Lee, Byung Hyung Choe, Soonja
Copyright Year	2009
Abstract	Stable poly(styrene-co-divinylbenzene) [P(St-co-DVB)] microspheres with narrow size distribution were synthesized in the presence of 2,2′-azobis(2,4-dimethyl valeronitrile) (V-65) and co-initiator in an acetone/water mixture in the precipitation polymerization at 53 °C for 24 h. Potassium peroxodisulfate (KPS), ammonium peroxodisulfate (APS) and sodium peroxodisulfate (NaPS) were used as co-initiators. The optimum ratio of acetone to water for the formation of a narrow distribution of P(St-co-DVB) particles was 49:11 (g/g). The optimum co-initiator compositions for narrow distribution were 9:1 (g/g) for V-65 to KPS, 11:1 for V-65 to APS and 6:1 for V-65 to NaPS. The yield for these compositions was 54∼57% and the largest particle size was obtained with the lowest zeta-potential and CV values. From the XPS measurements, the charge density was increased but the zeta potential decreased with increasing sulfur content, implying that the sulfate group provides the electrostatic stabilization on the particle surface. This suggested that the self-crosslinking between styrene and DVB, the electrostatic stabilization of initiators, and the balanced hydrophobic and hydrophilic properties of the solvents are responsible for the formation of stable P(St-co-DVB) spherical particles with narrow size distribution.
Starting Page	483
Ending Page	490
Page Count	8
File Format	PDF
ISSN	15985032
Journal	Macromolecular Research
Volume Number	17
Issue Number	7
e-ISSN	20927673
Language	English
Publisher	Springer-Verlag
Publisher Date	2009-01-01
Publisher Place	Berlin, Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	poly(styrene-co-divinylbenzene) precipitation polymerization co-initiator co-solvent Polymer Sciences Soft and Granular Matter, Complex Fluids and Microfluidics Physical Chemistry Characterization and Evaluation of Materials Nanochemistry Nanotechnology
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Materials Chemistry Chemical Engineering Polymers and Plastics

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