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Adsorption and Photocatalytic Degradation Kinetics of Pharmaceuticals by TiO$_{2}$ Nanowires During Water Treatment

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Adsorption and Photocatalytic Degradation Kinetics of Pharmaceuticals by TiO$_{2}$ Nanowires During Water Treatment

Content Provider	Springer Nature Link
Author	Hu, A. Zhang, X. Luong, D. Oakes, K. D. Servos, M. R. Liang, R. Kurdi, S. Peng, P. Zhou, Y.
Copyright Year	2012
Abstract	The adsorption and photocatalytic degradation of 15 different pharmaceuticals in the presence or absence of UV was comparatively studied using titanium dioxide (TiO$_{2}$) anatase and rutile nanowires as well as commercially available TiO$_{2}$ (P25) nanoparticles. Both anatase and rutile nanowires were grown under environmentally benign hydrothermal conditions. The kinetic adsorption studies demonstrate adsorption is usually complete within 20–40 min. The nanomaterials evaluated differed in photocatalytic efficiency by compound, with the UV-exposed anatase-phased nanowires being more effective at degrading venlafaxin, atorvastatin, ibuprofen, naproxen, gemfibrozil, lincomycin, norfluoxetine, diclofenac, and trimethoprim, while the rutile-phased nanowires were more effective for fluoxetine and norfluoxetine. The sole exposure to 265 nm UV leads to effectively decay sulfamethoxazole (SFX) and atrazine. Intermediate analysis unveils a higher mineralization of SFX is obtained with TiO$_{2}$ photocalytic degradation compared to the photolysis with a UVC at 254 nm. These initial studies provide mechanistic insight into the effectiveness of TiO$_{2}$ nanowires and nanoparticles for treatment of surface and drinking waters containing trace pharmaceutical residues.
Starting Page	443
Ending Page	449
Page Count	7
File Format	PDF
ISSN	18772641
Journal	Waste and Biomass Valorization
Volume Number	3
Issue Number	4
e-ISSN	1877265X
Language	English
Publisher	Springer Netherlands
Publisher Date	2012-06-30
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	TiO$_{2}$ nanowire Surface adsorption Photocatalytic degradation Pharmaceuticals Renewable and Green Energy Environmental Engineering/Biotechnology Waste Management/Waste Technology Industrial Pollution Prevention Engineering Environment
Content Type	Text
Resource Type	Article
Subject	Waste Management and Disposal Environmental Engineering Renewable Energy, Sustainability and the Environment

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