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| Content Provider | Springer Nature Link |
|---|---|
| Author | Lin, Qing quan Gu, Guo hua Wang, Hui Zhu, Ren feng Liu, You cai Fu, Jian gang |
| Copyright Year | 2016 |
| Abstract | In this study, a method for preparing pure manganese sulfate from low-grade ores with a granule mean size of 0.47 mm by direct acid leaching was developed. The effects of the types of leaching agents, sulfuric acid concentration, reaction temperature, and agitation rate on the leaching efficiency of manganese were investigated. We observed that sulfuric acid used as a leaching agent provides a similar leaching efficiency of manganese and superior selectivity against calcium compared to hydrochloric acid. The optimal leaching conditions in sulfuric acid media were determined; under the optimal conditions, the leaching efficiencies of Mn and Ca were 92.42% and 9.61%, respectively. Moreover, the kinetics of manganese leaching indicated that the leaching follows the diffusion-controlled model with an apparent activation energy of 12.28 kJ·mol$^{−1}$. The purification conditions of the leaching solution were also discussed. The results show that manganese dioxide is a suitable oxidant of ferrous ions and sodium dimethyldithiocarbamate is an effective precipitant of heavy metals. Finally, through chemical analysis and X-ray diffraction analysis, the obtained product was determined to contain 98% of MnSO$_{4}$·H$_{2}$O. |
| Starting Page | 491 |
| Ending Page | 500 |
| Page Count | 10 |
| File Format | |
| ISSN | 16744799 |
| Journal | International Journal of Minerals, Metallurgy, and Materials |
| Volume Number | 23 |
| Issue Number | 5 |
| e-ISSN | 1869103X |
| Language | English |
| Publisher | University of Science and Technology Beijing |
| Publisher Date | 2016-05-12 |
| Publisher Place | Beijing |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | manganese ore treatment manganese carbonate leaching leaching kinetics manganese sulfate Materials Science Metallic Materials Characterization and Evaluation of Materials Ceramics, Glass, Composites, Natural Methods Surfaces and Interfaces, Thin Films Tribology, Corrosion and Coatings |
| Content Type | Text |
| Resource Type | Article |
| Subject | Materials Chemistry Mechanics of Materials Metals and Alloys Geochemistry and Petrology Mechanical Engineering |
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