NDLI: Synthesis and characterization of interpenetrating polymer network of polyglycidyl methacrylate and acrylamide using selenonium ylide as an initiator

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Effect of reactive compatibilizers and impact modifier on the performance characteristics of polycarbonate/poly(acrylonitrile-butadiene-styrene) blends obtained from E-waste

International Journal of Plastics Technology : Volume 17, Issue 1, June 2013

International Journal of Plastics Technology : Volume 16

International Journal of Plastics Technology : Volume 15

International Journal of Plastics Technology : Volume 14

International Journal of Plastics Technology : Volume 13

Synthesis and characterization of interpenetrating polymer network of polyglycidyl methacrylate and acrylamide using selenonium ylide as an initiator

Content Provider	Springer Nature Link
Author	Singh, Anamika Kamal, Meet Singh, Dhruv K.
Copyright Year	2013
Abstract	Interpenetrating polymer network (IPN) based on polyglycidylmethacrylate (PGMA) and acrylamide (AAm) was synthesized using divinylbenzene (DVB) as a crosslinking agent and diphenylselenonium 2, 3, 4, 5-tetraphenylcyclopentadienylide (selenonium ylide) as a new radical initiator. A series of IPNs were prepared by varying the concentrations of AAm, PGMA, DVB and selenonium ylide in dioxan for 90 min at 80 ± 1 °C under an inert atmosphere of nitrogen. Dual phase morphology of the synthesized IPN was revealed by scanning electron microscopy (SEM). The properties like percentage swelling, average molecular weight of network between crosslinks (M$_{c}$) and young’s modulous were direct function of linear polymer [PGMA] and initiator [Ylide] where as inverse function of monomer [AAm] and crosslinker [DVB]. The differential scanning calorimetry (DSC) curve showed glass transition temperature at 127 °C. The synthesized IPN is thermally stable up to 450 °C. FTIR, $^{1}$H NMR and $^{13}$C NMR spectroscopic techniques were used for characterization of polyglycidylmethacrylate and IPN of polyglycidylmethacrylate (PGMA) and acrylamide (AAm). FTIR spectrum confirmed the presence of PGMA, AAm and DVB in the formed IPN by showing their characteristic bands. Similarly, $^{1}$H NMR and $^{13}$C NMR spectrum of the synthesized IPN also exhibit all characteristic peaks of PGMA, AAm and DVB in the formed IPN.
Starting Page	194
Ending Page	208
Page Count	15
File Format	PDF
ISSN	0972656X
Journal	International Journal of Plastics Technology
Volume Number	17
Issue Number	2
e-ISSN	0975072X
Language	English
Publisher	Springer India
Publisher Date	2013-11-23
Publisher Place	India
Access Restriction	Subscribed
Subject Keyword	Selenonium ylide Crosslink density Characterization IPN Polymer Sciences Materials Science
Content Type	Text
Resource Type	Article
Subject	Polymers and Plastics

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