NDLI: New terpolymers from n-butyl acrylate, glycidyl methacrylate and tetrahydrofurfuryl acrylate: Synthesis, characterisation and estimation of reactivity ratios

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New terpolymers from n-butyl acrylate, glycidyl methacrylate and tetrahydrofurfuryl acrylate: Synthesis, characterisation and estimation of reactivity ratios

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New terpolymers from n-butyl acrylate, glycidyl methacrylate and tetrahydrofurfuryl acrylate: Synthesis, characterisation and estimation of reactivity ratios

Content Provider	Springer Nature Link
Author	Azzahari, Ahmad Danial Yahya, Rosiyah Ahmad, Mohd Rais Zubir, Mohamad Bakri
Copyright Year	2014
Abstract	Development and practical application of multicomponent copolymerisation systems, such as terpolymerisation, is an on-going process because even a small addition of a particular comonomer may have a significant impact on the desired property. Commonly, three separate pairs of binary polymerisation experiments are carried out to obtain monomer reactivity ratios (MRR) values that relates to the ternary polymerisation reactions. However, the reaction conditions in each binary system may not be representative of the whole ternary system. The error-in-variables model (EVM) method is a relatively recent statistical approach to solving multi-response parameter estimation problems, with the advantage that all MRR parameters can be directly estimated from terpolymerisation data. New ternary copolymers derived from n-butyl acrylate (nBA), glycidyl methacrylate (GMA) and tetrahydrofurfuryl acrylate (THFA) were synthesised in solution at 70±1 °C in the presence of benzoyl peroxide (BPO) as a free radical initiator. The terpolymers were characterised by $^{1}$H NMR, $^{13}$C NMR and FTIR spectroscopic techniques. The terpolymer compositions were determined using $^{1}$H NMR analysis. The polydispersities of the terpolymers with values between 1.66 and 1.85 suggest a strong tendency for chain termination by disproportionation. The glass transition temperatures of the terpolymers are found to be between those of the corresponding homopolymers and relative to their content. Increase in the nBA or THFA contents and decrease in the GMA content in terpolymers results in a decrease in the glass transition temperatures. The determination of MRR for the ternary system was obtained by employing the EVM model. Experimental terpolymerisation data agree well with calculations based on the Alfrey-Goldfinger equation and the unitary and binary azeotropes were calculated.
Starting Page	437
Ending Page	445
Page Count	9
File Format	PDF
ISSN	12299197
Journal	Fibers and Polymers
Volume Number	15
Issue Number	3
e-ISSN	18750052
Language	English
Publisher	The Korean Fiber Society
Publisher Date	2014-05-09
Publisher Place	Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Terpolymerisation n-butyl acrylate Glycidyl methacrylate Tetrahydrofurfuryl acrylate Monomer reactivity ratios Polymer Sciences
Content Type	Text
Resource Type	Article
Subject	Chemistry Chemical Engineering Polymers and Plastics

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