NDLI: Reactive dyeing of meta-aramid fabrics photografted with dimethylaminopropyl methacrylamide

Content Provider	Springer Nature Link
Author	Kim, Eun Min Min, Byung Gil Jang, Jinho
Copyright Year	2011
Abstract	Aramid fibers have been known to difficult to dye with conventional dyes and dyeing techniques because of its extremely high crystallinity and compactness. In order to make the aramid fibers dyeable to a bright color in deep shade, meta-aramid fabrics were photografted under continuous UV irradiation with dimethylaminopropyl methacrylamide (DMAPMA) and benzophenone as a monomer and a hydrogen-abstractable photoinitiator respectively. Several factors affecting the photografting treatment of the meta-aramid fabrics were investigated including monomer and photoinitiator concentrations. ATR, ESCA and SEM analysis indicated significant alterations on the chemical structure and atomic composition of the photografted fabric surface and the fabric surface was covered with the grafted polymers. While the pristine meta-aramid fabrics showed no appreciable dyeability to the α-bromoacrylamide type reactive dyes, the grafted aramid fabrics showed the remarkably enhanced dyeability to the reactive dyes, which was proportional to the graft yield indicating the covalent bond formation between the dyes and the secondary amino groups in the grafted DMAPMA. In case of C.I. Reactive Red 84, a K/S value of 14.8 can be obtained with the grafted meta-aramid fabrics with a graft yield of 7.6 % (w/w). Also and the color fastness properties of the dyed fabrics was excellent in the conditions of washing, rubbing and solar irradiation.
Starting Page	580
Ending Page	586
Page Count	7
File Format	PDF
ISSN	12299197
Journal	Fibers and Polymers
Volume Number	12
Issue Number	5
e-ISSN	18750052
Language	English
Publisher	The Korean Fiber Society
Publisher Date	2011-07-30
Publisher Place	Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Meta-aramid Photografting UV irradiation Reactive dyes Dyeability Polymer Sciences
Content Type	Text
Resource Type	Article
Subject	Chemistry Chemical Engineering Polymers and Plastics

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