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Mechanical and thermal properties of polypropylene (PP) composites filled with CaCO$_{3}$ and shell waste derived bio-fillers

Content Provider	Springer Nature Link
Author	Yao, Zhitong Xia, Meisheng Ge, Liuqin Chen, Tao Li, Haiyan Ye, Ying Zheng, Hao
Copyright Year	2014
Abstract	The clam shell (CS) waste was first modified by furfural and hydrochloric acid to prepare fillers FCS and ACS, which were then used as fillers in polypropylene (PP), as well as the commercial calcium carbonate (CC). These fillers were characterized and analyzed by means of X-ray diffraction (XRD), atomic force microscopy (AFM), particle size analyzer, Fourier transformed infrared spectroscopy (FTIR) and contact angle measurement. The mechanical and thermal properties of PP composites were investigated as well. XRD analysis indicated that the major crystalline phase of CC was calcite; of shell waste derived fillers, calcite and aragonite. The CC was fully hydrophobic, while the shell derived fillers were amphiphilic. Mechanical property studies showed that the incorporation of FCS played the role mainly of toughening the PP; of CC, CS and ACS, that of reinforcing. The optimum filler contents of CS, ACS and FCS could reach 5, 7 and 15 wt.%, respectively, to obtain a good balance between fracture toughness and stiffness of the PP composites. Polarized optical microscopy (POM) observation indicated that the inclusion of these fillers could promote the heterogeneous nucleation of PP.
Starting Page	1278
Ending Page	1287
Page Count	10
File Format	PDF
ISSN	12299197
Journal	Fibers and Polymers
Volume Number	15
Issue Number	6
e-ISSN	18750052
Language	English
Publisher	The Korean Fiber Society
Publisher Date	2014-07-09
Publisher Place	Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Shell waste Modification Bio-filler Calcium carbonate Polypropylene Polymer Sciences
Content Type	Text
Resource Type	Article
Subject	Chemistry Chemical Engineering Polymers and Plastics

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