NDLI: Effect of co-monomer ratio in ABS and wood content on processing and properties in wood/ABS composites

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Effect of co-monomer ratio in ABS and wood content on processing and properties in wood/ABS composites

Content Provider	Springer Nature Link
Author	Threepopnatkul, P. Teppinta, W. Sombatsompop, N.
Copyright Year	2011
Abstract	Acrylonitrile-Butadiene-Styrene copolymers (ABS) reinforced with wood flour were investigated for rheological, mechanical and thermal properties. Three grades of commercial ABS resin (high flow (HF-ABS), medium impact (MI-ABS) and super high impact (SI-ABS) grades) were characterized using H-NMR and elemental analysis for the determination of co-monomer content. Wood flour from Para rubber trees treated with N-2 (aminoethyl)-3-(aminopropyl) trimethoxy silane was blended with ABS in the melt blending process using a twin-screw extruder. Wood flour contents used in this work were 0.0 %, 9.1 %, and 33.3 % wt. The composites with higher acrylonitrile contents showed higher melt viscosity especially at the low shear rate. Carreau’s model was used for curve-fitting. The extrudate swell ratio of the composites tended to increase at the shear rate of 10–500 s$^{−1}$ and then decreased dramatically once the shear rate were further applied. Neat ABS and wood/ABS composites with higher butadiene content illustrated a higher swelling ratio. The neat MI-ABS and composites showed the highest ultimate tensile strength and modulus due to the butadiene content effect. As the wood flour loading was increased, the tensile modulus of all ABS composites increased with the sacrifice of the tensile strength of composites. The elongation at break and impact strength were noticeably the highest for wood/SI-ABS composites among all because of the effect of rubbery butadiene content. Thermal stability of plastic in 9.1 % wood in HF-ABS composites was improved compared with the neat HF-ABS due to the low acrylonitrile content.
Starting Page	1007
Ending Page	1013
Page Count	7
File Format	PDF
ISSN	12299197
Journal	Fibers and Polymers
Volume Number	12
Issue Number	8
e-ISSN	18750052
Language	English
Publisher	The Korean Fiber Society
Publisher Date	2011-12-07
Publisher Place	Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Thermoplastics Reinforcement Mechanical properties Processing Polymer Sciences
Content Type	Text
Resource Type	Article
Subject	Chemistry Chemical Engineering Polymers and Plastics

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