NDLI: Simultaneous Determination of Multiclass Pesticides and Antibiotics in Honey Samples Based on Ultra-High Performance Liquid Chromatography-Tandem Mass Spectrometry

Content Provider	Springer Nature Link
Author	Orso, Débora Floria, Luana Ribeiro, Lucila C. Bandeira, Nelson M. G. Prestes, Osmar D. Zanella, Renato
Copyright Year	2015
Abstract	A simple, fast, and efficient method was developed for simultaneous determination of 79 pesticides and 13 antibiotics compounds of different chemical classes of pesticides and antibiotics in honey samples by ultra-high performance liquid chromatography with tandem mass spectrometry (UHPLC-MS/MS). The sample preparation procedure includes homogenization with McIlvaine buffer 0.1 mol L$^{−1}$ (pH 4), followed by extraction with acetonitrile and cleanup with florisil, using dispersive solid phase extraction (d-SPE). The proposed method was validated with good results, such as linearity (r $^{2}$ > 0.9901), normality, and independence of the evaluated data, as well as recoveries between 70 and 120 % with relative standard deviation (RSD) <20 % for most of the compounds spiked from 0.1 to 200 μg kg$^{−1}$. The experimental method limits of detection and quantification were from 0.03 to 1.51 μg kg$^{−1}$ and from 0.1 to 5 μg kg$^{−1}$, respectively, for the pesticides. For the antibiotics, the decision limits (0.1 to 2 μg g$^{−1}$) and the detection capacity (0.12 to 2.81 μg g$^{−1}$) were below the maximum residue limits (MRLs) established for honey by the Brazilian and European legislation. The method was successfully applied to real samples from different botanical and geographic origins. From them, 44 % presented residues from 0.12 to 10 μg kg$^{−1}$ of one or more analytes. The proposed method combines the advantages of a quick sample preparation step with the selectivity and sensitivity of the UHPLC-MS/MS and proved to be suitable for routine analyses.
Starting Page	1638
Ending Page	1653
Page Count	16
File Format	PDF
ISSN	19369751
Journal	Food Analytical Methods
Volume Number	9
Issue Number	6
e-ISSN	1936976X
Language	English
Publisher	Springer US
Publisher Date	2015-10-26
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Honey Pesticides Antibiotics UHPLC-MS/MS Food Science Chemistry/Food Science Microbiology Analytical Chemistry
Content Type	Text
Resource Type	Article
Subject	Analytical Chemistry Safety Research Safety, Risk, Reliability and Quality Applied Microbiology and Biotechnology Food Science

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