NDLI: Preparation of Biopolymers from Plant Oils in Green Media

Content Provider	Springer Nature Link
Author	Liu, Zengshe
Copyright Year	2013
Abstract	The conversion of plant oils to polymers has attracted renewed attention in recent years to replace or augment the traditional petro-chemical based polymers and resins. This is because of concern for the environment, waste disposal, and depletion of fossil and non renewable feedstocks. In this study, the polymerization of soybean oil (SBO), epoxidized soybean oil (ESO), and euphorbia oil (EuO) in carbon dioxide (CO$_{2}$) media (subcritical and supercritical conditions) catalyzed by Lewis acid were reported. The molecular structures of SBO, ESO, and EuO affected the polymerization. It showed that epoxidized plant oils are easier to polymerize than SBO. The resulting polymers were characterized by FTIR, $^{1}$H-NMR, $^{13}$C-NMR, solid state $^{13}$C-NMR spectroscopies, differential scanning calorimetry, thermogravimetric analysis, and gel permeation chromatography.
Starting Page	1230
Ending Page	1236
Page Count	7
File Format	PDF
ISSN	19391234
Journal	BioEnergy Research
Volume Number	6
Issue Number	4
e-ISSN	19391242
Language	English
Publisher	Springer US
Publisher Date	2013-03-17
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Soybean oil Epoxidized soybean oil Euphorbia oil Ring-opening polymerization Supercritical and subcritical carbon dioxide Plant Sciences Plant Genetics & Genomics Plant Breeding/Biotechnology Plant Ecology Wood Science & Technology
Content Type	Text
Resource Type	Article
Subject	Renewable Energy, Sustainability and the Environment Agronomy and Crop Science

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