NDLI: Tuning porosity via control of interpenetration in a zinc isonicotinate metal organic framework

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Tuning porosity via control of interpenetration in a zinc isonicotinate metal organic framework

Content Provider	Springer Nature Link
Author	NANDI, SHYAMAPADA VAIDHYANATHAN, RAMANATHAN
Copyright Year	2014
Abstract	Metal organic frameworks (MOFs) are a class of porous solids formed by linking metal centres or metal clusters by suitable organic ligands capable of generating porosity in the microporous and mesoporous regimes. They have been investigated extensively for their gas storage applications in the last two decades. Interpenetration is nature’s way of avoiding excessive free-space within the large porous networks by growing identical but independent networks within a parent network to decrease the solvent accessible voids and increase stability. A major challenge in MOF synthesis involves minimizing or completely eliminating the extent. In this paper, we report a zinc isonicotinate (or pyridyl-4-carboxylate, 4-PyC) MOF, 1, prepared by tuning the synthesis conditions to minimize interpenetration. The three-fold interpenetration presented in this material is unusual and has been compared to the other zinc isonicotinates to identify the differences contributing to the improved porosity. In addition, the thermal decomposition of 1 in an oxygen-deficient medium has been shown to yield significantly porous carbon embedded with ZnO nanoparticles. Graphical Abstract Control of interpenetration in a highly interpenetrated Zinc isonicotinate system has been achieved via systematic investigation of the synthesis conditions. Also, the conversion of the metal organic framework into a porous carbon embedded with ZnO nanoparticles under an oxygen-deficient atmosphere has been demonstrated.
Starting Page	1393
Ending Page	1398
Page Count	6
File Format	PDF
ISSN	09743626
Journal	Journal of Chemical Sciences
Volume Number	126
Issue Number	5
e-ISSN	09737103
Language	English
Publisher	Springer India
Publisher Date	2014-11-04
Publisher Institution	Indian Academy of Sciences
Publisher Place	India
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Metal organic framework zinc isonicotinate unusual three-fold interpenetration post-combustion porosity Chemistry/Food Science
Content Type	Text
Resource Type	Article
Subject	Chemistry

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