NDLI: A two-dimensional yttrium phthalate coordination polymer, [Y$_{4}$(H$_{2}$O)$_{2}$(C$_{8}$H$_{4}$O$_{4}$)$_{6}$]$_{∞}$, exhibiting different coordination geometries

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A two-dimensional yttrium phthalate coordination polymer, [Y$_{4}$(H$_{2}$O)$_{2}$(C$_{8}$H$_{4}$O$_{4}$)$_{6}$]$_{∞}$, exhibiting different coordination geometries

Content Provider	Springer Nature Link
Author	Thirumurugan, A. Natarajan, Srinivasan
Copyright Year	2003
Abstract	A hydrothermal reaction of a mixture of Y(NO$_{3}$)$_{3}$, 1,2-benzenedicarboxylic acid (1,2-BDC) and NaOH gives rise to a new yttrium phthalate coordination polymer, [Y$_{4}$H$_{2}$O$_{2}$C$_{8}$H$_{4}$O$_{4}$)$_{6}$]$_{∞}$,I. The Y ions inI are present in four different coordination environments with respect to the oxygen atoms (CN6 = octahedral, CN7 = pentagonal bipyramid, CN8 = dodecahedron and CN9 = capped square anti-prism). The oxygen atoms of the 1,2-BDC are fully deprotonated, and show variations in their connectivity with Y atoms. The Y atoms themselves are connected through their vertices forming infinite Y-O-Y one-dimensional chains. The Y-O-Ychains are cross-linked by the 1,2-BDC anions forming a corrugated layer structure. The layers are supported by favourableπ…π interactions between the benzene rings of the 1,2-BDC anions. The variations in the coordination environment of the Y atoms and the presence of Y-O-Y interactions along with the favourableπ…π interactions between the benzene rings from different layers are noteworthy structural features. Crystal data: triclinic, space group =P−1 (no. 2),a = 12.6669 (2),b = 13.8538 (2),c = 16.0289 Å,α = 75.20 (1),β = 69.012 (1),γ= 65.529 (1)°,V = 2371.28 (7) Å$^{3}$,D $_{calc}$ = 1.922 g cm$^{−1}$, μ($_{MoKα}$) = 4.943 mm$^{−1}$. A total of 9745 reflections collected and merged to give 6566 unique reflections (R $_{int}$ = 0.0292) of which 5252 withI>2σ(I) were considered to be observed. FinalR $_{2}$ = 0.0339,wR $_{2}$ = 0.0724 andS = 1.036 were obtained for 704 parameters.
Starting Page	573
Ending Page	586
Page Count	14
File Format	PDF
ISSN	02534134
Journal	Journal of Chemical Sciences
Volume Number	115
Issue Number	5-6
e-ISSN	09737103
Language	English
Publisher	Springer India
Publisher Date	2003-01-01
Publisher Institution	Indian Academy of Sciences
Publisher Place	New Delhi
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Yttrium phthalic acid coordination polymer layered structure Chemistry/Food Science
Content Type	Text
Resource Type	Article
Subject	Chemistry

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