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Synthesis, structure, thermal and NLO characterization of 4-hydroxy tetramethylpiperazinium picrate crystals

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Synthesis, structure, thermal and NLO characterization of 4-hydroxy tetramethylpiperazinium picrate crystals

Content Provider	Springer Nature Link
Author	DAS, SAMAR K
Copyright Year	2012
Abstract	Good quality single crystals of 4-hydroxy tetramethylpiperazinium picrate (TMPP) were grown by slow evaporation solution growth method at room temperature. The average dimensions of the grown crystals were 0.6 × 0.2 × 0.2 cm$^{3}$. The solubility of the compound was estimated using methanol and acetone. The elemental analysis confirms the formation of the compound in the stoichiometric proportion. The UV-visible transmittance study indicates that the crystal possesses minimum transmittance at 370 nm and no absorption at 470–900 nm. The Bragg peaks obtained in the powder X-ray diffraction pattern confirm its crystallinity. The thermal behaviour of the crystal was investigated using thermogravimetric (TG) and differential thermal analysis (DTA) techniques. The structure of the compound was determined by using single crystal X-ray diffraction method. The compound was found to be crystallize in the monoclinic space group P2$_{(1)}$/c (a = 6.9513(8)Å, b = 11.8016(14)Å, c = 22.018(2)Å, α = 90.00°, β = 92.575(2)°, γ = 90.00°). The thermal anomalies observed in the differential scanning calorimetry (DSC) heating and cooling cycles indicate the occurrence of first order phase transition. Fourier transform infrared (FTIR) and polarized Raman spectral analyses were used to confirm the presence of various functional groups in the compound. The nonlinear optical property (NLO) of the crystal was analysed by Kurtz-Perry powder technique and found that the compound has SHG efficiency 1.5 times greater that of potassium dihydrogen phosphate (KDP). Graphical Abstract A picric acid salt, 4-hydroxy tetramethylpiperazinium picrate was synthesized and crystallized. Thermal and spectral characterizations were carried out. The XRD structure determination indicated that the compound crystallized in monoclinic system with space group P2(1)/c. The SHG efficiency of the crystal was 1.5 times greater than that of KH2DPO4.
Starting Page	951
Ending Page	961
Page Count	11
File Format	PDF
ISSN	09743626
Journal	Journal of Chemical Sciences
Volume Number	124
Issue Number	4
e-ISSN	09737103
Language	English
Publisher	Springer-Verlag
Publisher Date	2012-08-17
Publisher Institution	Indian Academy of Sciences
Publisher Place	India
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Crystal growth thermal analysis differential scanning calorimetry nonlinear optical materials single crystal X-ray diffraction FTIR spectrum Chemistry/Food Science
Content Type	Text
Resource Type	Article
Subject	Chemistry

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