NDLI: Study of dielectric and ferroelectric properties of five-layer Aurivillius oxides: A$_{2}$Bi$_{4}$Ti$_{5}$O$_{18}$ (A = Ba, Pb and Sr) synthesized by solution combustion route

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Study of dielectric and ferroelectric properties of five-layer Aurivillius oxides: A$_{2}$Bi$_{4}$Ti$_{5}$O$_{18}$ (A = Ba, Pb and Sr) synthesized by solution combustion route

Content Provider	Springer Nature Link
Author	DUBEY, SHIVANGI KURCHANIA, RAJNISH
Copyright Year	2015
Abstract	This paper presents the ferroelectric and dielectric properties of five-layer Aurivillius oxides (Ba$_{2}$Bi$_{4}$Ti$_{5}$O$_{18}$, Pb$_{2}$Bi$_{4}$Ti$_{5}$O$_{18}$ and Sr$_{2}$Bi$_{4}$Ti$_{5}$O$_{18}$) prepared by a solution combustion route with glycine as a fuel at low calcination temperature. The phase formation of these materials with pseudo-tetragonal structure was achieved after calcination at 750°C for 3 h; as confirmed by X-ray diffraction studies. Scanning electron microscopy of the sintered ceramics shows that the grains exhibit a plate-like morphology. The ferroelectric to paraelectric transition temperature (T $_{c}$) for Ba-, Pb- and Sr-based bismuth titanate ceramics was found to be 350, 280 and 260°C, respectively. All three materials show multiple relaxation phenomena and their electrical conductivity was found to be temperature dependent. The Pb$_{2}$Bi$_{4}$Ti$_{5}$O$_{18}$ ceramic possessed the highest value of activation energy (0.68 eV) and hence shows better ferroelectric properties, as compared to barium and strontium bismuth titanates.
Starting Page	1881
Ending Page	1889
Page Count	9
File Format	PDF
ISSN	02504707
Journal	Bulletin of Materials Science
Volume Number	38
Issue Number	7
e-ISSN	09737669
Language	English
Publisher	Indian Academy of Sciences
Publisher Date	2015-12-05
Publisher Institution	Indian Academy of Sciences
Publisher Place	Bangalore, India
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Ceramics X-ray diffraction dielectric properties ferroelectric properties. Materials Science Engineering
Content Type	Text
Resource Type	Article
Subject	Mechanics of Materials Materials Science

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