NDLI: Proton transport properties of tin phosphate, chromotropic acid anchored onto tin phosphate and tin phenyl phosphonate

Content Provider	Springer Nature Link
Author	SUMEJ, CHITHRA SHARMILA, P P THARAYIL, NISHA J
Copyright Year	2013
Abstract	Tin (IV) phosphates of the class of tetravalent metal acid (TMA) salts have been synthesized by sol–gel method. The functionalized materials of tin (IV) phosphate (SnP) like chromotropic acid anchored tin phosphate (SnPCA) and tin phenyl phosphonate (SnPP) were also synthesized. These materials have been characterized for elemental analysis (ICP–AES), thermal analysis, X-ray analysis and FTIR spectroscopy. Chemical resistivity of these materials has been accessed in acidic, basic and organic solvent media. The proton present in the structural hydroxyl groups indicates good potential for TMA salts to exhibit solid-state proton conduction. The transport properties of these materials have been explored by measuring specific proton conductance at different temperatures. Based on the specific conduction data and Arrhenius plots, a suitable mechanism has been proposed.
Starting Page	129
Ending Page	133
Page Count	5
File Format	PDF
ISSN	02504707
Journal	Bulletin of Materials Science
Volume Number	36
Issue Number	1
e-ISSN	09737669
Language	English
Publisher	Springer-Verlag
Publisher Date	2013-04-03
Publisher Institution	Indian Academy of Sciences
Publisher Place	India
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Proton transport properties tin phosphate tin phenyl phosphonate Materials Science Engineering
Content Type	Text
Resource Type	Article
Subject	Mechanics of Materials Materials Science

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