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Study of hot corrosion resistance of electroless nickel coating with different content of phosphorous in molten salt deposit Na$_{2}$SO$_{4}$–NaCl at 650°C

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Study of hot corrosion resistance of electroless nickel coating with different content of phosphorous in molten salt deposit Na$_{2}$SO$_{4}$–NaCl at 650°C

Content Provider	Springer Nature Link
Author	Ghaderi, M. Rezagholizadeh, M. Nasiri Vatan, H. Ebrahimi Kahrizsangi, R.
Copyright Year	2015
Abstract	In this research, the hot corrosion behavior of electroless nickel-(4, 7, 9, and 12 wt % P) was studied in 70 wt % Na$_{2}$SO$_{4}$–30 wt % NaCl (3 and 6 mg/cm$^{2}$) molten salt on a copper substrate. After being plated with a thickness of 25 ± 3 µm, the specimens were annealed at 400°C for 1 hour, and then the hardness of each was measured by the Vickers hardness test method. The hot corrosion test was performed at 650°C for 20 hours inside the furnace at a rate of 4°C/min under atmospheric conditions. The results showed that Ni—7 wt % P and Ni—12 wt % P electroless coatings included the highest and the lowest hot corrosion resistance, respectively. The difference in the weight increase of the hot corrosion of Ni—12 wt % P coating was about 8 times as much as that of Ni—7 wt % P, and the difference in thermal expansion between the substrate and the coating was responsible for the cracks in the coating. Diffusion of the molten salt through these cracks expanded and reached the intersection of the coating and the substrate. The results of the XRD showed the formation of NiSO$_{4}$, NiO, and Cu on the coating surface after the hot corrosion test.
Starting Page	367
Ending Page	373
Page Count	7
File Format	PDF
ISSN	10683755
Journal	Surface Engineering and Applied Electrochemistry
Volume Number	51
Issue Number	4
e-ISSN	19348002
Language	English
Publisher	Allerton Press
Publisher Date	2015-09-08
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	electroless Ni—P molten salt hot corrosion hot mount Manufacturing, Machines, Tools
Content Type	Text
Resource Type	Article
Subject	Industrial and Manufacturing Engineering Surfaces, Coatings and Films Surfaces and Interfaces

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