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| Content Provider | Springer Nature Link |
|---|---|
| Author | Shmelev, V. M. Nikolaev, V. M. |
| Copyright Year | 2008 |
| Abstract | A new method for the partial oxidation of methane in a rapid compression machine with internal heat recovery was proposed and examined. A rapid compression machine on the basis of an internal combustion engine with a cylinder divided by a partition with a crossflow orifice into two chambers was considered. Internal heat recovery was implemented using a thermal activator installed in the smaller (auxiliary) chamber. Calculations demonstrated that this method makes it possible to convert methane in methane-air mixtures with a hydrocarbon content of up to 24% at degrees of compression of 10 to 20 and peak pressures below 200 atm. A region (determined by the crossflow orifice diameter and degree of compression) within which a heat recovery cycle exists was revealed. It was demonstrated that, for mixtures containing 22% methane or less, the extent of conversion exceeds 93%, a value that makes it possible to generate useful energy at degrees of compression above 10. |
| Starting Page | 431 |
| Ending Page | 436 |
| Page Count | 6 |
| File Format | |
| ISSN | 19907931 |
| Journal | Russian Journal of Physical Chemistry B |
| Volume Number | 2 |
| Issue Number | 3 |
| e-ISSN | 19907923 |
| Language | English |
| Publisher | Nauka/Interperiodica |
| Publisher Date | 2008-08-10 |
| Publisher Place | Moscow |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Physical Chemistry |
| Content Type | Text |
| Resource Type | Article |
| Subject | Physical and Theoretical Chemistry |
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